{2-[2-azido-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-3,5,6-trimethoxy-4-methyl-benzyloxy}-tert-butyl-dimethyl-silane

Base Information

Chemical Name:{2-[2-azido-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-3,5,6-trimethoxy-4-methyl-benzyloxy}-tert-butyl-dimethyl-silane
CAS No.:886450-30-2
Molecular Formula:C₂₄H₄₁N₃O₆Si
Molecular Weight:495.692
Hs Code.:

{2-[2-azido-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-3,5,6-trimethoxy-4-methyl-benzyloxy}-<i>tert</i>-butyl-dimethyl-silane

Synonyms:{2-[2-azido-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-3,5,6-trimethoxy-4-methyl-benzyloxy}-tert-butyl-dimethyl-silane

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Chemical Property of {2-[2-azido-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-3,5,6-trimethoxy-4-methyl-benzyloxy}-tert-butyl-dimethyl-silane

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Technology Process of {2-[2-azido-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-3,5,6-trimethoxy-4-methyl-benzyloxy}-tert-butyl-dimethyl-silane

There total 1 articles about {2-[2-azido-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-3,5,6-trimethoxy-4-methyl-benzyloxy}-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 271578-70-2
4-[2-(tert-butyl-dimethyl-silanyloxymethyl)-3,4,6-trimethoxy-5-methyl-phenyl]-but-2-en-1-ol

: 886450-30-2
{2-[2-azido-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-3,5,6-trimethoxy-4-methyl-benzyloxy}-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: molecular sieves 4 Angstroem; Ti(OiPr)4; tBuOOH / D-diethyl tartrate / 24 h / -20 °C

1.2: Ti(OiPr)2(N₃)2 / benzene / 5 h / 80 °C

2.1: 100 percent / TsOH*H₂O / acetone / 0.17 h / 25 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; 4 A molecular sieve; toluene-4-sulfonic acid; Diethyl tartrate; In acetone; 1.1: Sharpless epoxidation;
DOI:10.1002/anie.200503982

Reference yield: 100.0%

: 886450-30-2
{2-[2-azido-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-3,5,6-trimethoxy-4-methyl-benzyloxy}-tert-butyl-dimethyl-silane

: 24424-99-5
di-tert-butyl dicarbonate

: 886450-31-3
[2-[2-(tert-butyl-dimethyl-silanyloxymethyl)-3,4,6-trimethoxy-5-methyl-phenyl]-1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-carbamic acid tert-butyl ester

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethyl acetate; at 25 ℃; for 5h;
DOI:10.1002/anie.200503982

Reference yield:

: 886450-30-2
{2-[2-azido-2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-3,5,6-trimethoxy-4-methyl-benzyloxy}-tert-butyl-dimethyl-silane

: 886450-32-4
[1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-2-(2-hydroxymethyl-3,4,6-trimethoxy-5-methyl-phenyl)-ethyl]-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / H₂ / Pd/C / ethyl acetate / 5 h / 25 °C

2: 99 percent / tetrabutylammonium fluoride / tetrahydrofuran / 1 h / 25 °C

With tetrabutyl ammonium fluoride; hydrogen; palladium on activated charcoal; In tetrahydrofuran; ethyl acetate;
DOI:10.1002/anie.200503982