[(4,4'-di-tert-butyl-2,2'-dipyridyl)Pt(Me)(NH₂Ph)][trifluoroacetate]

Base Information

• Chemical Name: [(4,4'-di-tert-butyl-2,2'-dipyridyl)Pt(Me)(NH₂Ph)][trifluoroacetate]
• CAS No.: 1220521-08-3
• Molecular Formula: C₂F₃O₂*C₂₅H₃₄N₃Pt
• Molecular Weight: 684.661
• Mol file: 1220521-08-3.mol

Synonyms:[(4,4'-di-tert-butyl-2,2'-dipyridyl)Pt(Me)(NH₂Ph)][trifluoroacetate]

Chemical Property of [(4,4'-di-tert-butyl-2,2'-dipyridyl)Pt(Me)(NH₂Ph)][trifluoroacetate]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(4,4'-di-tert-butyl-2,2'-dipyridyl)Pt(Me)(NH₂Ph)][trifluoroacetate]

There total 1 articles about [(4,4'-di-tert-butyl-2,2'-dipyridyl)Pt(Me)(NH₂Ph)][trifluoroacetate] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

(4,4'-di-tert-butyl-2,2'-bipyridine)methyl(trifluoroacetato)platinum(II) (177593-38-3) + aniline (62-53-3) → [(4,4'-di-tert-butyl-2,2'-dipyridyl)Pt(Me)(NH2Ph)][trifluoroacetate] (1220521-08-3)

Guidance literature:

In toluene; (N2); ligand added to a soln. of Pt complex, sealed, heated to 90°C for 24 h; evapd. (vac.), reconstituted in THF, filtered, concd. (vac.), dissolved in CH2Cl2, pptd. (hexanes), sepd., dried (vac.); elem. anal.;

DOI:10.1021/ic200153n

Reference yield: 85.0%

[(4,4'-di-tert-butyl-2,2'-dipyridyl)Pt(Me)(NH2Ph)][trifluoroacetate] (1220521-08-3) → (4,4'-di-tert-butyl-2,2'-dipyridyl)Pt(Me)(NHPh) (1220521-09-4)

Guidance literature:

With NaN(Si(CH₃)3)2; In tetrahydrofuran; benzene; (N2); a THF soln. of NaN(Si(CH3)3)2 added to a C6H6 soln. of Pt complex,stirred for 2 h; filtered, evapd. (vac.); elem. anal.;

DOI:10.1021/ic200153n

upstream raw materials:

(4,4'-di-tert-butyl-2,2'-bipyridine)methyl(trifluoroacetato)platinum(II)

aniline

Downstream raw materials:

(4,4'-di-tert-butyl-2,2'-dipyridyl)Pt(Me)(NHPh)