(η6-1-isopropyl-4-methylbenzene)(N-(p-tosyl)-1,2-diamino-1,1,2,2-tetramethylethane)ruthenium(II)

Base Information

• Chemical Name: (η6-1-isopropyl-4-methylbenzene)(N-(p-tosyl)-1,2-diamino-1,1,2,2-tetramethylethane)ruthenium(II)
• CAS No.: 1070163-25-5
• Molecular Formula: C₂₃H₃₄N₂O₂RuS
• Molecular Weight: 503.671
• Mol file: 1070163-25-5.mol

Synonyms:(η6-1-isopropyl-4-methylbenzene)(N-(p-tosyl)-1,2-diamino-1,1,2,2-tetramethylethane)ruthenium(II)

Chemical Property of (η6-1-isopropyl-4-methylbenzene)(N-(p-tosyl)-1,2-diamino-1,1,2,2-tetramethylethane)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η6-1-isopropyl-4-methylbenzene)(N-(p-tosyl)-1,2-diamino-1,1,2,2-tetramethylethane)ruthenium(II)

There total 1 articles about (η6-1-isopropyl-4-methylbenzene)(N-(p-tosyl)-1,2-diamino-1,1,2,2-tetramethylethane)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

[RuCl2(p-cymene)]2 (658044-18-9,128706-72-9,52462-29-0) + N-(p-tosyl)-1,2-diamino-1,1,2,2-tetramethylethane (1070163-22-2) → (η6-1-isopropyl-4-methylbenzene)(N-(p-tosyl)-1,2-diamino-1,1,2,2-tetramethylethane)ruthenium(II) (1070163-25-5)

Guidance literature:

With potassium hydroxide; In dichloromethane; byproducts: H2; under Ar, Schlenk technique; CH2Cl2 added to mixt. of Ru complex and diamino compd., mixt. stirred at room temp. for 10 min, KOH powder added, mixt. stirred at room temp. for 15 min, O2-free H2O added; aq. soln. removed with canula, org. phase dried with CaH2, filtered under Ar, filtrate evapd. under vac.;

DOI:10.1016/j.molcata.2008.05.009

upstream raw materials:

[RuCl₂(p-cymene)]2

N-(p-tosyl)-1,2-diamino-1,1,2,2-tetramethylethane