(η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)]

Base Information

• Chemical Name: (η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)]
• CAS No.: 640298-73-3
• Molecular Formula: C₂₂H₂₈FeN₂
• Molecular Weight: 376.325

Synonyms:(η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)]

Chemical Property of (η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)]

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Technology Process of (η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)]

There total 2 articles about (η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

dilithioferrocene*0.67 N,N,N',N'-tetramethylethylenediamine + 3,5-bis[(dimethylamino)methyl]phenyl iodide → ferrocene (102-54-5,55404-68-7) + (η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)] (640298-73-3) + [Fe(η5-C5H4-4-(C6H3(CH2NMe2)2-2,6))2] (640298-72-2)

Guidance literature:

With [Pd(PPh₃)2]; In tetrahydrofuran; (N2); at 0°C, Fe complex dissolved in THF, ZnCl2 added in a portion, stirred for 1 h at this temp., a soln. of Pd(PPh3)2 added, stirred for 5 min, a soln. of IC6H3(CH2NMe2)2-3,5 added, allowed to warm to 25°C, stirred for 2 d; quenched with a soln. of NaOH, the aq. phase sepd., extd. with CHCl3, the combined org. phases dried (MgSO4), filtered, evapd. (vac.), chromd. (alumina, Et2O, Et2O/THF, MeOH), obtained as an oil; elem. anal.;

DOI:10.1016/S0022-328X(03)00753-8

Reference yield: 27.0%

ferrocene boronic acid + 3,5-bis[(dimethylamino)methyl]phenyl iodide → (η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)] (640298-73-3)

Guidance literature:

With NaOH; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In 1,2-dimethoxyethane; under N2 atm. to Fe complex and aryl iodide in DME 3 M NaOH was added, ((dppf)PdCl2) was added at 25°C and heated at reflux for 6 days; react. mixt. was cooled to 25°C, dissolved in CHCl3 followed by addn. water, aq. phase was extd. with Et2O, dried over MgSO4, filtered and evapd. in vacuo, chromy. on neutral alumina; elem. anal.;

DOI:10.1016/j.ica.2006.05.045

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