2,5-diethyl-4-trimethylsilylphenylboronic acid

Base Information

Chemical Name:2,5-diethyl-4-trimethylsilylphenylboronic acid
CAS No.:1048958-27-5
Molecular Formula:C₁₃H₂₃BO₂Si
Molecular Weight:250.221
Hs Code.:

Synonyms:2,5-diethyl-4-trimethylsilylphenylboronic acid

Suppliers and Price of 2,5-diethyl-4-trimethylsilylphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,5-diethyl-4-trimethylsilylphenylboronic acid

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,5-diethyl-4-trimethylsilylphenylboronic acid

There total 2 articles about 2,5-diethyl-4-trimethylsilylphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1048958-26-4
(4-bromo-2,5-diethylphenyl)trimethylsilane

: 1048958-27-5
2,5-diethyl-4-trimethylsilylphenylboronic acid

Guidance literature:: (4-bromo-2,5-diethylphenyl)trimethylsilane; With n-butyllithium; In tetrahydrofuran; diethyl ether; hexane; at -78 - -10 ℃; Inert atmosphere;

With Triisopropyl borate; In tetrahydrofuran; diethyl ether; hexane; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1021/ja801924y

Reference yield: 72.0%

: 5419-55-6
Triisopropyl borate

: 1048958-26-4
(4-bromo-2,5-diethylphenyl)trimethylsilane

: 1048958-27-5
2,5-diethyl-4-trimethylsilylphenylboronic acid

Guidance literature:: With CH₃CH₂CH₂CH₂Li; In tetrahydrofuran; diethyl ether; addn. of hexane soln. of butyllithium to soln. of benzene deriv. in ether and THF at -78°C under Ar, warming to -10.degre.C, cooling to -78°C, addn. of borate deriv., warming to room temp., keeping overnight under Ar; addn. of water, stirring for 15 min, evapn., dissolving in CH2Cl2, washing with water, extn. (CH2Cl2) of aq. phase, evapn. of combined organic phases, chromy. (silica gel, pentane/ethyl acetate (100/0 to 65/35)), NMRand MS;
DOI:10.1021/ja801924y

Reference yield: 73.0%

: 3,8-bis(4-bromo-2'-pyridyl)-4,7-phenanthroline

: 1048958-27-5
2,5-diethyl-4-trimethylsilylphenylboronic acid

: 1048958-28-6
3,8-bis(4-(2,5-diethyl-4-trimethylsilylphenyl)-2'-pyridyl)-4,7-phenanthroline

Guidance literature:: With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In N,N-dimethyl-formamide; at 120 ℃; for 50h; Inert atmosphere;
DOI:10.1021/ja801924y