Aurate(1-), tetrachloro-, cesium, (SP-4-1)-

Base Information

• Chemical Name: Aurate(1-), tetrachloro-, cesium, (SP-4-1)-
• CAS No.: 13682-60-5
• Molecular Formula: AuCl4 . Cs
• Molecular Weight: 471.684
• European Community (EC) Number: 237-189-6
• DSSTox Substance ID: DTXSID90929559
• Mol file: 13682-60-5.mol

Synonyms:Aurate(1-), tetrachloro-, cesium, (SP-4-1)-;13682-60-5;Cesium tetrachloroaurate(III);cesium;gold(3+);tetrachloride;EINECS 237-189-6;Aurate(1-), tetrachloro-, cesium (1:1), (SP-4-1)-;AuCl4.Cs;Au-Cl4.Cs;DTXSID90929559;Caesium gold(3+) chloride (1/1/4)

Chemical Property of Aurate(1-), tetrachloro-, cesium, (SP-4-1)-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -11.98650
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 471.744483
• Heavy Atom Count: 6
• Complexity: 0

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Cl-].[Cs+].[Au+3]

Technology Process of Aurate(1-), tetrachloro-, cesium, (SP-4-1)-

There total 8 articles about Aurate(1-), tetrachloro-, cesium, (SP-4-1)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

hydrogen tetrachloroaurate(III) tetrahydrate + cesium chloride (15690-63-8,64704-31-0,7647-17-8) → cesium tetrachlorido aurate(III) (13682-60-5)

Guidance literature:

In hydrogenchloride; addn. of satd. aq. CsCl to HAuCl4 in 3% HCl (ice-bath, pptn.); yellow hydrated complex was immediately formed;; collection (filtration), washing (cold H2O); hydrate-free complex obtained after drying in vac. dessicator for several days;;

DOI:10.1039/DT9910003121

Reference yield:

cesium chloroaurate → cesium tetrachlorido aurate(III) (13682-60-5) + gold (7440-57-5,457905-15-6)

Guidance literature:

With H₂O;

Reference yield:

caesium nitrate + chloroauric acid → cesium tetrachlorido aurate(III) (13682-60-5)

Guidance literature:

In not given; excess of CsNO3; cooling 0°C; filtration with ice water; wahsing with alc. and ether;

DOI:10.1021/ja01412a018

upstream raw materials:

cesium chloride

gold(III) chloride

Downstream raw materials:

gold