cis-cyclohexylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II)

Base Information

• Chemical Name: cis-cyclohexylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II)
• CAS No.: 111848-49-8
• Molecular Formula: C₃₂H₆₀P₂Pt
• Molecular Weight: 701.856
• Mol file: 111848-49-8.mol

Synonyms:cis-cyclohexylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II)

Chemical Property of cis-cyclohexylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II)

Chemical Property:

Purity/Quality:

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Technology Process of cis-cyclohexylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II)

There total 3 articles about cis-cyclohexylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

cis-chloro(cyclohexyl){bis(dicyclohexylphosphino)ethane}platinum(II) (111848-58-9) → cis-cyclohexylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II) (111848-49-8)

Guidance literature:

With Na{HB(OMe)3}; In tetrahydrofuran; addn. of Na{HB(OMe)3} to cis-chloro(cyclohexyl){bis(dicyclohexylphosphino)ethane}platinum(II) in THF with immediate cloudiness, after 3 h quenched by aq. NH4Cl at 0°C; layers sepd., extd. with ether, solvent removal by evapn., resulting oil dissolved in min. of THF, 2 parts methanol added, crystn. at -10°C, suction filtrn.;

DOI:10.1021/ja00213a016

Reference yield: 45.0%

cis-[bis-(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II) + methane (34557-54-5,27936-85-2) → cis-cyclohexylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II) (111848-49-8) + ethylene{bis(dicyclohexylphosphino)ethane}platinum(0) (102286-39-5) + cis-methylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II) (111848-50-1) + 2,2-dimethylpropane (463-82-1)

Guidance literature:

In cyclohexane; thermolysis of cis-hydridoneopentyl{bis(dicyclohexylphosphino)ethane}platinum(II) in cyclohexane under methane via supposed {bis(dicyclohexylphosphino)ethane}platinum(0) at 45°C for 39h at 2050 psi; Kinetics;

DOI:10.1021/ja00213a016

Reference yield: 12.0%

cis-[bis-(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II) + cyclohexane (110-82-7,25012-93-5) → cis-cyclohexylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II) (111848-49-8) + 2,2-dimethylpropane (463-82-1)

Guidance literature:

In cyclohexane; thermolysis of cis-hydridoneopentyl{bis(dicyclohexylphosphino)ethane}platinum(II) in cyclohexane via supposed {bis(dicyclohexylphosphino)ethane}platinum(0) at 45.5°C for 21.5h; Kinetics;

DOI:10.1021/ja00213a016

upstream raw materials:

cyclohexane

methane

cis-chloro(cyclohexyl){bis(dicyclohexylphosphino)ethane}platinum(II)