RUBIDIUM VANADATE (META)

Base Information

• Chemical Name: RUBIDIUM VANADATE (META)
• CAS No.: 13597-45-0
• Molecular Formula: O₃RbV
• Molecular Weight: 184.407
• Mol file: 13597-45-0.mol

Synonyms:Vanadate (VO31-),rubidium (9CI);Vanadic acid (HVO3), rubidium salt (8CI);Rubidiummetavanadate;

Chemical Property of RUBIDIUM VANADATE (META)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 114.40000
• Density: g/cm³
• LogP: -0.71280

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of RUBIDIUM VANADATE (META)

There total 16 articles about RUBIDIUM VANADATE (META) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

rubidium carbonate + vanadia → rubidium metavanadate (13597-45-0)

Guidance literature:

In solid;

Reference yield:

3Rb(1+)*V5O14(3-)=Rb3V5O14 → rubidium metavanadate (13597-45-0) + Rb(1+)*V3O8(1-) = RbV3O8

Guidance literature:

With air; In neat (no solvent, solid phase); heating V compd. to 500°C (10°C/min) under air; cooling to room temp. (10°C/min) under air, XRD;

DOI:10.1021/ic1008297

Reference yield:

Rb(2+)*CO3(2-)=RbCO3 + vanadia → rubidium metavanadate (13597-45-0)

Guidance literature:

Rb⁽²⁺⁾*CO₃^(2-)=RbCO₃; vanadia; In acetone;

at 400 ℃; for 2h; Calcination;

DOI:10.1039/c6nj03823a

upstream raw materials:

rubidium nitrate

Refernces

• 1、 Slobodin,Surat. "Subsolidus phase relations in the systems M2+O-M 2+O-V2O5 (M+ = Li, Na, K, Rb, Cs; M2+ = Mg, Ca)". . p. 188 - 194. Retrieved 2004.
• 2、 Yahia, Hamdi Ben,Gaudin, Etienne,Darriet, Jacques. "Crystal structures of new pyrovanadates A2MnV2O 7 (A = Rb, K)". . p. 873 - 880. Retrieved 2007.
• 3、 Patwe, S. J.,Rao, U. R. K.. "Mode of thermal decomposition of diammonium lithium oxyfluoro vanadate (DALOFV) and diammonium rubidium oxyfluoro vanadate (DAROFV)". . p. 205 - 210. Retrieved 1995.
• 4、 Gobrecht, H.,Heinsohn, G.. "". . p. 350 - 360. Retrieved 1957.
• 5、 Krasil'nikov,Perelyaeva,Baklanova. "Synthesis, structure, and properties of M[VO2(XO 4)(H2O)2] · H2O (X = S, M = K, Rb, NH4, Tl; X = Se, M = K, Rb, NH4)". . p. 325 - 330. Retrieved 2011.
• 6、 Krasil'Nikov,Tyutyunnik,Zubkov,Berger,Perelyaeva,Baklanova. "Synthesis, structure, and properties of M3VO2(SO 4)2 (M = Rb, Cs)". . p. 1331 - 1338. Retrieved 2010.
• 7、 Zou, Guohong,Jo, Hongil,Lim, Seong-Ji,You, Tae-Soo,Ok, Kang Min. "Rb3VO(O2)2CO3: A Four-in-One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second-Harmonic Generation Response". . p. 8619 - 8622. Retrieved 2018.
• 8、 Adams, David M.,Fletcher, Patrick A.. "Vibrational spectroscopy at high pressure: part 53. Alkali metavanadates and copper metagermanate". . p. 233 - 242. Retrieved 1988.
• 9、 Zakharova,Podval'Naya,Kuznetsov. "XPS study of nanorods of doped vanadium oxide M x V 2O5 ? nH2O (M = Na, K, Rb, Cs)". . p. 267 - 272. Retrieved 2011/06/20.