2-(3',5'-dimethoxybiphenyl-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline

Base Information

• Chemical Name: 2-(3',5'-dimethoxybiphenyl-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline
• CAS No.: 1356826-16-8
• Molecular Formula: C₂₇H₂₀N₄O₂
• Molecular Weight: 432.481
• Mol file: 1356826-16-8.mol

Synonyms:2-(3',5'-dimethoxybiphenyl-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline

Chemical Property of 2-(3',5'-dimethoxybiphenyl-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(3',5'-dimethoxybiphenyl-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline

There total 1 articles about 2-(3',5'-dimethoxybiphenyl-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.2%

1,10-phenanthroline-5,6-dione (27318-90-7) + 3',5'-dimethoxybiphenyl-4-carbaldehyde (1356826-17-9) → 2-(3',5'-dimethoxybiphenyl-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline (1356826-16-8)

Guidance literature:

With ammonium acetate; In acetic acid; for 5h; Reflux;

DOI:10.1016/j.poly.2011.11.049

Reference yield: 80.7%

ammonium hexafluorophosphate + iron(II) chloride tetrahydrate + 2-(3',5'-dimethoxybiphenyl-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline (1356826-16-8) → Fe(2-(3',5'-dimethoxybiphenyl-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)3(PF6)2

Guidance literature:

In water; N,N-dimethyl-formamide; soln. of phenanthroline in DMF added dropwise to soln. of Zn-salt in DMF, refluxed for 12 h, cooled to room temp., treated in situ anion exchange reaction by adding aq. NH4PF6; ppt. filtered, washed (H2O, diethyl ether), dried (vac.); elem. anal.;

DOI:10.1016/j.poly.2011.11.049

Reference yield: 79.8%

ammonium hexafluorophosphate + 2-(3',5'-dimethoxybiphenyl-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline (1356826-16-8) + zinc(II) acetate dihydrate (5970-45-6) → Zn(2-(3',5'-dimethoxybiphenyl-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)3(PF6)2

Guidance literature:

In water; N,N-dimethyl-formamide; soln. of phenanthroline in DMF added dropwise to soln. of Zn-salt in DMF, refluxed for 12 h, cooled to room temp., treated in situ anion exchange reaction by adding aq. NH4PF6; ppt. filtered, washed (H2O, diethyl ether), dried (vac.); elem. anal.;

DOI:10.1016/j.poly.2011.11.049

upstream raw materials:

1,10-phenanthroline-5,6-dione

3',5'-dimethoxybiphenyl-4-carbaldehyde