2,3-O-isopropylidene-1-O-methyl-4-O-phenoxythiocarbonyl-α-L-lyxopyranose

Base Information

Chemical Name:2,3-O-isopropylidene-1-O-methyl-4-O-phenoxythiocarbonyl-α-L-lyxopyranose
CAS No.:727416-02-6
Molecular Formula:C₁₆H₂₀O₆S
Molecular Weight:340.397
Hs Code.:

Synonyms:2,3-O-isopropylidene-1-O-methyl-4-O-phenoxythiocarbonyl-α-L-lyxopyranose

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Chemical Property of 2,3-O-isopropylidene-1-O-methyl-4-O-phenoxythiocarbonyl-α-L-lyxopyranose

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Technology Process of 2,3-O-isopropylidene-1-O-methyl-4-O-phenoxythiocarbonyl-α-L-lyxopyranose

There total 1 articles about 2,3-O-isopropylidene-1-O-methyl-4-O-phenoxythiocarbonyl-α-L-lyxopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 2495-99-0
methyl 2,3-O-isopropylidene-α-L-lyxopyranoside

: 1005-56-7
phenylcarbonochloridothioate

: 727416-02-6
2,3-O-isopropylidene-1-O-methyl-4-O-phenoxythiocarbonyl-α-L-lyxopyranose

Guidance literature:: With dmap; In acetonitrile; at 0 ℃; for 5h;
DOI:10.1021/jo040130g

Reference yield: 62.0%

: 66680-87-3,66680-88-4,79159-76-5
(2-phenylvinyl)tributylstannane

: 727416-02-6
2,3-O-isopropylidene-1-O-methyl-4-O-phenoxythiocarbonyl-α-L-lyxopyranose

: 727416-03-7
2,3-O-isopropylidene-1-O-methyl-4-C-(2-phenylethenyl)-α-L-lyxopyranose

Guidance literature:: With 2,2'-azobis(isobutyronitrile); In benzene; Heating;
DOI:10.1021/jo040130g

Reference yield:

: 727416-02-6
2,3-O-isopropylidene-1-O-methyl-4-O-phenoxythiocarbonyl-α-L-lyxopyranose

: 727416-05-9
1-[4-deoxy-4-C-hydroxymethyl-3,6-O-(1,1,3,3-tetraisopropyldisiloxan-1,3-diyl)-2-O-phenoxythiocarbonyl-α-L-lyxopyranosyl]thymine

Guidance literature:: Multi-step reaction with 9 steps

1.1: 62 percent / azobisisobutyronitrile / benzene / Heating

2.1: N-methylmorpholine-N-oxide; osmium tetraoxide / dioxane; H₂O / 20 °C

2.2: NaIO₄ / H₂O; dioxane / 3 h / 0 - 20 °C

3.1: 127 mg / NaBH₄ / ethanol; H₂O / 2 h / 20 °C

4.1: 77 percent / trifluoroacetic acid / H₂O / 0.08 h

5.1: 89 percent / pyridine / 3 h / 20 °C

6.1: 38 percent / SnCl₂ / acetonitrile / 39 h / Heating

7.1: 78 percent / NH₃ / methanol / 7 h / 20 °C

8.1: 89 percent / imidazole / dimethylformamide / 20 - 30 °C

9.1: 89 percent / 4-dimethylaminopyridine / acetonitrile / 0 - 20 °C

With pyridine; 1H-imidazole; dmap; sodium tetrahydroborate; osmium(VIII) oxide; 2,2'-azobis(isobutyronitrile); ammonia; 4-methylmorpholine N-oxide; trifluoroacetic acid; tin(ll) chloride; In 1,4-dioxane; methanol; ethanol; water; N,N-dimethyl-formamide; acetonitrile; benzene;
DOI:10.1021/jo040130g