2-methylene-3-(trans-3-tert-butyldimethylsiloxyocten-1-yl)-4-cumyloxycyclopentanone

Base Information

Chemical Name:2-methylene-3-(trans-3-tert-butyldimethylsiloxyocten-1-yl)-4-cumyloxycyclopentanone
CAS No.:70302-45-3
Molecular Formula:C₂₉H₄₆O₃Si
Molecular Weight:470.768
Hs Code.:

Synonyms:2-methylene-3-(trans-3-tert-butyldimethylsiloxyocten-1-yl)-4-cumyloxycyclopentanone

Suppliers and Price of 2-methylene-3-(trans-3-tert-butyldimethylsiloxyocten-1-yl)-4-cumyloxycyclopentanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-methylene-3-(trans-3-tert-butyldimethylsiloxyocten-1-yl)-4-cumyloxycyclopentanone

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Technology Process of 2-methylene-3-(trans-3-tert-butyldimethylsiloxyocten-1-yl)-4-cumyloxycyclopentanone

There total 2 articles about 2-methylene-3-(trans-3-tert-butyldimethylsiloxyocten-1-yl)-4-cumyloxycyclopentanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 60134-93-2
3-(tert-butyldimethylsilyloxy)oct-1-yne

: 70302-45-3
2-methylene-3-(trans-3-tert-butyldimethylsiloxyocten-1-yl)-4-cumyloxycyclopentanone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Cp₂ZrHCl, 2.) Ni(AcAc)2/DiBAH

2: 89 percent / Et₃N, CH₃SO₂Cl / CH₂Cl₂ / 1 h / -25 °C

With bis(acetylacetonate)nickel(II); Schwartz's reagent; diisobutylaluminium hydride; methanesulfonyl chloride; triethylamine; In dichloromethane;
DOI:10.1021/ja00524a017

Reference yield:

: 65457-77-4
4-<(1,1'-dimethylbenzyl)oxy>-2-cyclopentenone

: 70302-45-3
2-methylene-3-(trans-3-tert-butyldimethylsiloxyocten-1-yl)-4-cumyloxycyclopentanone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Cp₂ZrHCl, 2.) Ni(AcAc)2/DiBAH

2: 89 percent / Et₃N, CH₃SO₂Cl / CH₂Cl₂ / 1 h / -25 °C

With bis(acetylacetonate)nickel(II); Schwartz's reagent; diisobutylaluminium hydride; methanesulfonyl chloride; triethylamine; In dichloromethane;
DOI:10.1021/ja00524a017

Reference yield:

: 73448-13-2
tert-butyldimethylsilyl hex-5-yn-1-yl ether

: 70302-45-3
2-methylene-3-(trans-3-tert-butyldimethylsiloxyocten-1-yl)-4-cumyloxycyclopentanone

: 73448-22-3,73448-24-5
(+/-)-2-decarboxy-2-tert-butyldimethylsiloxymethyl-5-(E)-prostaglandin E₂ 9-cumyl ether 15-tert-butyldimethylsilyl ether

Guidance literature:: With bis(acetylacetonate)nickel(II); Schwartz's reagent; diisobutylaluminium hydride; Yield given. Multistep reaction; 2.) toluene, THF, 0 deg C;
DOI:10.1021/ja00524a017