3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanal

Base Information

Chemical Name:3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanal
CAS No.:443283-24-7
Molecular Formula:C₂₉H₄₆O₃Si₂
Molecular Weight:498.853
Hs Code.:

3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-5-(<i>tert</i>-butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanal

Synonyms:3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanal

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Chemical Property of 3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanal

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Technology Process of 3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanal

There total 6 articles about 3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1438399-45-1
C₂₉H₄₈O₃Si₂

: 443283-24-7
3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanal

Guidance literature:: With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1002/chem.201201332

Reference yield: 88.0%

: C₃₀H₄₈O₂Si₂

: 443283-24-7
3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanal

Guidance literature:: C₃₀H₄₈O₂Si₂; With ozone; In methanol; dichloromethane; at -78 ℃;

With dimethylsulfide; In methanol; dichloromethane; at -78 - 20 ℃; for 5h;
DOI:10.1039/d1cc04058h

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 443283-24-7
3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2,4-dimethyl-pentanal

Guidance literature:: Multi-step reaction with 3 steps

1.1: copper(l) iodide; methyllithium / tetrahydrofuran; diethyl ether / 8 h / 0 °C / Inert atmosphere

1.2: 0.5 h / 0 °C / Inert atmosphere

2.1: lithium triethylborohydride / tetrahydrofuran / 0.5 h / 0 - 25 °C / Inert atmosphere

3.1: [bis(acetoxy)iodo]benzene; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / dichloromethane / 0.5 h / 0 °C

With copper(l) iodide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; methyllithium; lithium triethylborohydride; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1002/chem.201201332