prop-2-en-1-yl N-{2-[(3,3-dimethylcycloprop-1-en-1-yl)(hydroxy)methyl]phenyl}-N-(prop-2-en-1-yl)carbamate

Base Information

Chemical Name:prop-2-en-1-yl N-{2-[(3,3-dimethylcycloprop-1-en-1-yl)(hydroxy)methyl]phenyl}-N-(prop-2-en-1-yl)carbamate
CAS No.:1314234-90-6
Molecular Formula:C₁₉H₂₃NO₃
Molecular Weight:313.397
Hs Code.:

Synonyms:prop-2-en-1-yl N-{2-[(3,3-dimethylcycloprop-1-en-1-yl)(hydroxy)methyl]phenyl}-N-(prop-2-en-1-yl)carbamate

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Chemical Property of prop-2-en-1-yl N-{2-[(3,3-dimethylcycloprop-1-en-1-yl)(hydroxy)methyl]phenyl}-N-(prop-2-en-1-yl)carbamate

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Technology Process of prop-2-en-1-yl N-{2-[(3,3-dimethylcycloprop-1-en-1-yl)(hydroxy)methyl]phenyl}-N-(prop-2-en-1-yl)carbamate

There total 3 articles about prop-2-en-1-yl N-{2-[(3,3-dimethylcycloprop-1-en-1-yl)(hydroxy)methyl]phenyl}-N-(prop-2-en-1-yl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 1314234-89-3
prop-2-en-1-yl N-(2-formylphenyl)-N-(prop-2-en-1-yl)carbamate

: 23534-97-6
1,1,3‐tribromo‐2,2‐dimethylcyclopropane

: 1314234-90-6
prop-2-en-1-yl N-{2-[(3,3-dimethylcycloprop-1-en-1-yl)(hydroxy)methyl]phenyl}-N-(prop-2-en-1-yl)carbamate

Guidance literature:: 1,1,3‐tribromo‐2,2‐dimethylcyclopropane; With n-butyllithium; In hexanes; diethyl ether; at -78 - -10 ℃; for 1h;

prop-2-en-1-yl N-(2-formylphenyl)-N-(prop-2-en-1-yl)carbamate; In tetrahydrofuran; hexanes; diethyl ether; at -78 - 50 ℃; for 0.25h;

With ammonium chloride; In hexanes; diethyl ether; water; Saturated solution;
DOI:10.1002/anie.201101220

Reference yield:

: 1309934-63-1
prop-2-en-1-yl N-(2-formylphenyl)carbamate

: 1314234-90-6
prop-2-en-1-yl N-{2-[(3,3-dimethylcycloprop-1-en-1-yl)(hydroxy)methyl]phenyl}-N-(prop-2-en-1-yl)carbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 6.5 h / 80 °C

2.1: n-butyllithium / hexanes; diethyl ether / 1 h / -78 - -10 °C

2.2: 0.25 h / -78 - 50 °C

2.3: Saturated solution

With n-butyllithium; potassium carbonate; In hexanes; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1002/anie.201101220

Reference yield:

: 345201-68-5
prop-2-en-1-yl N-[2-(hydroxymethyl)phenyl]carbamate

: 1314234-90-6
prop-2-en-1-yl N-{2-[(3,3-dimethylcycloprop-1-en-1-yl)(hydroxy)methyl]phenyl}-N-(prop-2-en-1-yl)carbamate

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium acetate; pyridinium chlorochromate / diethyl ether; dichloromethane / 2.5 h / 20 °C / Molecular sieve

2.1: potassium carbonate / N,N-dimethyl-formamide / 6.5 h / 80 °C

3.1: n-butyllithium / hexanes; diethyl ether / 1 h / -78 - -10 °C

3.2: 0.25 h / -78 - 50 °C

3.3: Saturated solution

With n-butyllithium; sodium acetate; potassium carbonate; pyridinium chlorochromate; In hexanes; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/anie.201101220