[(2R,3S,4R,5R,6S)-3,4-bis(acetyloxy)-5-acetamido-6-(2-nitrophenoxy)oxan-2-yl]methyl acetate

Base Information

Chemical Name:[(2R,3S,4R,5R,6S)-3,4-bis(acetyloxy)-5-acetamido-6-(2-nitrophenoxy)oxan-2-yl]methyl acetate
CAS No.:13089-26-4
Molecular Formula:C20H24 N2 O11
Molecular Weight:468.417
Hs Code.:
Mol file:13089-26-4.mol

Synonyms:13089-26-4;2-Nitrophenyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-b-D-glucopyranoside;(2'-NITRO)PHENYL-2-ACETAMIDO-3,4,6-TRI-O-ACETYL-2-DEOXY-beta-D-GLUCOPYRANOSIDE;[(2R,3S,4R,5R,6S)-3,4-bis(acetyloxy)-5-acetamido-6-(2-nitrophenoxy)oxan-2-yl]methyl acetate;[(2R,3S,4R,5R,6S)-5-acetamido-3,4-diacetyloxy-6-(2-nitrophenoxy)oxan-2-yl]methyl acetate;Glucopyranoside, o-nitrophenyl 2-acetamido-2-deoxy-, triacetate, alpha-D- (8CI);AKOS002687864;Z57103015;o-Nitrophenyl 2-Acetamido-2-deoxy-3,4,6-tri-O-acetyl- alpha -D-glucopyranoside

Suppliers and Price of [(2R,3S,4R,5R,6S)-3,4-bis(acetyloxy)-5-acetamido-6-(2-nitrophenoxy)oxan-2-yl]methyl acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
o-Nitrophenyl2-Acetamido-2-deoxy-3,4,6-tri-O-acetyl-β-D-galactopyranoside
250mg
$ 1230.00

TRC
o-Nitrophenyl2-Acetamido-2-deoxy-3,4,6-tri-O-acetyl-β-D-galactopyranoside
25mg
$ 155.00

American Custom Chemicals Corporation
2-NITROPHENYL 2-ACETAMIDO-3,4,6-TRI-O-ACETYL-2-DEOXY-BETA-D-GLUCOPYRANOSIDE 95.00%
250MG
$ 1871.10

American Custom Chemicals Corporation
2-NITROPHENYL 2-ACETAMIDO-3,4,6-TRI-O-ACETYL-2-DEOXY-BETA-D-GLUCOPYRANOSIDE 95.00%
25MG
$ 739.20

AK Scientific
2-Nitrophenyl2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyranoside
5g
$ 1072.00

Total 6 raw suppliers

Chemical Property of [(2R,3S,4R,5R,6S)-3,4-bis(acetyloxy)-5-acetamido-6-(2-nitrophenoxy)oxan-2-yl]methyl acetate

Chemical Property:

PSA：172.28000
LogP:1.54380
Solubility.:Ethanol, Ethyl Acetate, Methanol
XLogP3:0.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:11
Rotatable Bond Count:10
Exact Mass:468.13800959
Heavy Atom Count:33
Complexity:753

Purity/Quality:

99%, ^*data from raw suppliers

o-Nitrophenyl2-Acetamido-2-deoxy-3,4,6-tri-O-acetyl-β-D-galactopyranoside ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)NC1C(C(C(OC1OC2=CC=CC=C2[N+](=O)[O-])COC(=O)C)OC(=O)C)OC(=O)C
Isomeric SMILES:CC(=O)N[C@@H]1[C@H]([C@@H]([C@H](O[C@H]1OC2=CC=CC=C2[N+](=O)[O-])COC(=O)C)OC(=O)C)OC(=O)C
Uses o-Nitrophenyl 2-Acetamido-2-deoxy-3,4,6-tri-O-acetyl-β-D-galactopyranoside (cas# 13089-26-4) is a compound useful in organic synthesis.

Technology Process of [(2R,3S,4R,5R,6S)-3,4-bis(acetyloxy)-5-acetamido-6-(2-nitrophenoxy)oxan-2-yl]methyl acetate

There total 4 articles about [(2R,3S,4R,5R,6S)-3,4-bis(acetyloxy)-5-acetamido-6-(2-nitrophenoxy)oxan-2-yl]methyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 88-75-5,78813-12-4
2-hydroxynitrobenzene

: 3068-34-6
Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester

: 13089-26-4,13264-91-0
o-nitrophenyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: With 15-crown-5; sodium hydrogencarbonate; In acetonitrile; at 20 ℃;
DOI:10.1023/A:1012988719296

Reference yield:

: 10034-19-2,1191127-63-5
1,3,4,6-tetra-O-acetyl-2-amino-2-deoxy-α-D-glucopyranose hydrochloride

: 13089-26-4,13264-91-0
o-nitrophenyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine

2: acetic acid anhydride; hydrogen chloride

3: acetone; aq. NaOH solution

With pyridine; hydrogenchloride; sodium hydroxide; acetic anhydride; acetone;
DOI:10.1039/jr9570004754

Reference yield:

: 3006-60-8,4539-83-7,6730-10-5,7772-79-4,7784-54-5,10385-50-9,14086-90-9,26151-16-6,76375-60-5,76375-61-6,95341-98-3,95341-99-4,134451-91-5,134451-96-0,136982-81-5,145375-11-7,148347-15-3
2-acetamido-1,3,4,6-tetra-O-acetyl-2-deoxy-β-D-glucopyranose

: 13089-26-4,13264-91-0
o-nitrophenyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: acetic acid anhydride; hydrogen chloride

2: acetone; aq. NaOH solution

With hydrogenchloride; sodium hydroxide; acetic anhydride; acetone;
DOI:10.1039/jr9570004754