((2R,3R)-3-(((2R,4S,5R)-5-(tert-butyldimethylsilyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl)oxiran-2-yl)methanol

Base Information

Chemical Name:((2R,3R)-3-(((2R,4S,5R)-5-(tert-butyldimethylsilyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl)oxiran-2-yl)methanol
CAS No.:315204-08-1
Molecular Formula:C₂₀H₃₂O₅Si
Molecular Weight:380.557
Hs Code.:

Synonyms:((2R,3R)-3-(((2R,4S,5R)-5-(tert-butyldimethylsilyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl)oxiran-2-yl)methanol

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Chemical Property of ((2R,3R)-3-(((2R,4S,5R)-5-(tert-butyldimethylsilyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl)oxiran-2-yl)methanol

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Technology Process of ((2R,3R)-3-(((2R,4S,5R)-5-(tert-butyldimethylsilyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl)oxiran-2-yl)methanol

There total 9 articles about ((2R,3R)-3-(((2R,4S,5R)-5-(tert-butyldimethylsilyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl)oxiran-2-yl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1438399-36-0
C₂₈H₄₅NO₆SSi

: 315204-08-1
((2R,3R)-3-(((2R,4S,5R)-5-(tert-butyldimethylsilyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl)oxiran-2-yl)methanol

Guidance literature:: With lithium triethylborohydride; In tetrahydrofuran; at 0 - 25 ℃; for 0.5h; Inert atmosphere;
DOI:10.1002/chem.201201332

Reference yield: 87.0%

: 315204-07-0
(E)-4-[(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-but-2-en-1-ol

: 315204-08-1
((2R,3R)-3-(((2R,4S,5R)-5-(tert-butyldimethylsilyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl)oxiran-2-yl)methanol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; (-)-diethyl tartrate; 4 A molecular sieve; In 2,2,4-trimethylpentane; dichloromethane; at -20 - 20 ℃;
DOI:10.1016/S0040-4020(01)00164-8

Reference yield:

: 315204-07-0
(E)-4-[(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-but-2-en-1-ol

: C₂₀H₃₂O₅Si

: 315204-08-1
((2R,3R)-3-(((2R,4S,5R)-5-(tert-butyldimethylsilyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl)oxiran-2-yl)methanol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate; In decane; dichloromethane; at -25 - 0 ℃; for 15h; optical yield given as %de; diastereoselective reaction; Inert atmosphere; Molecular sieve;