TITANIUM(VI) SULFIDE

Base Information

• Chemical Name: TITANIUM(VI) SULFIDE
• CAS No.: 12423-80-2
• Molecular Formula: S₃Ti
• Molecular Weight: 144.078
• Mol file: 12423-80-2.mol

Synonyms:Titaniumsulfide; Titanium trisulfide

Chemical Property of TITANIUM(VI) SULFIDE

Chemical Property:

• PSA: 96.27000
• LogP: 1.94460

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TITANIUM(VI) SULFIDE

There total 15 articles about TITANIUM(VI) SULFIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

titanium (7440-32-6) + sulfur (7704-34-9) → titanium trisulfide (12423-80-2)

Guidance literature:

In neat (no solvent); heating of mixt. of educts in an evacuated quartz tube in a furnace with a temp. gradient of 400 to 900°C;

DOI:10.1016/0022-4596(82)90373-5

Reference yield:

titanium(IV) oxide + sulfur (7704-34-9) → titanium trisulfide (12423-80-2)

Guidance literature:

With boron; In neat (no solvent); byproducts: B2O3; 2 short silica tubes were filled with powder oxide and a mixt. of boron and sulfur (3:4:9), placed in a larger silica tube, the latter was evacuated, sealed, heated at 50°C per hour to 400°C and kept for 24 h; cooled to room temp., the sulfide was washed with CS2 and deionized water or MeOH to remove unreacted S, boron sulfides and B2O3; atomic absorbtion spectrometric anal., powder X-ray diffraction data;

DOI:10.1021/ja0392521

Reference yield:

titanium (7440-32-6) + sulfur (7704-34-9) → titanium trisulfide (12423-80-2)

Guidance literature:

at 500 ℃; for 150h; Sealed tube;

DOI:10.1134/S0022476617050250

upstream raw materials:

titanium

sulfur

sulfur

oxygen

Downstream raw materials:

sulfur

Refernces

• 1、 Zanini. "REVERSIBILITY OF SODIUM INSERTION IN TRANSITION METAL TRISULFIDES.". . p. 588 - 593. Retrieved 1985.
• 2、 Chang, H. S. W.,Schleich, D. M.. "". . p. 62 - 70. Retrieved 1992.
• 3、 Nakhal, Suliman,Lerch, Martin,Koopman, Jeroen,Islam, Mazharul M.,Bredow, Thomas. "Crystal structure of 3R-LiTiS2 and its stability compared to other polymorphs". . p. 2822 - 2825. Retrieved 2013.
• 4、 Endo, Kazuhiro,Ihara, Hideo,Watanabe, Kazuhiro,Gonda, Shun-Ichi. "". . p. 215 - 218. Retrieved 1981.
• 5、 Fleet,Harmer,Liu,Nesbitt. "Polarized X-ray absorption spectroscopy and XPS of TiS3: S K- and Ti L-edge XANES and S and Ti 2p XPS". . p. 133 - 145. Retrieved 2005.
• 6、 Ma, Jingjing,Liu, Xiaoyang,Cao, Xuejing,Feng, Shouhua,Fleet, Michael E.. "Bundle of nanobelts up to 4 cm in length: One-step synthesis and preparation of titanium trisulfide (TiS3) nanomaterials". . p. 519 - 522. Retrieved 2006.
• 7、 Sieber,Fotouhi,Gorochov. "CRYSTAL GROWTH, CHARACTERIZATION AND PHOTOELECTROCHEMICAL PROPERTIES OF Zr1 - xTixS3 (0 less than x less than . 33).". . p. 1477 - 1484. Retrieved 1983.
• 8、 Finkman, E.,Fisher, B.. "". . p. 25 - 28. Retrieved 1984.