(6S)-2,6-dimethyl-2-icosene

Base Information

Chemical Name:(6S)-2,6-dimethyl-2-icosene
CAS No.:230966-14-0
Molecular Formula:C₂₂H₄₄
Molecular Weight:308.591
Hs Code.:

Synonyms:(6S)-2,6-dimethyl-2-icosene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (6S)-2,6-dimethyl-2-icosene

Chemical Property:

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Technology Process of (6S)-2,6-dimethyl-2-icosene

There total 1 articles about (6S)-2,6-dimethyl-2-icosene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 67214-54-4
(R)-citronellyl tosylate

: 143-15-7
1-dodecylbromide

: 646-31-1
tetracosane

: 230966-14-0
(6S)-2,6-dimethyl-2-icosene

Guidance literature:: 1-dodecylbromide; With magnesium; In tetrahydrofuran;

(R)-citronellyl tosylate; With dilithium tetrachlorocuprate; In tetrahydrofuran; at -78 - 20 ℃; Title compound not separated from byproducts;
DOI:10.1271/bbb.68.1768

Reference yield:

: 230966-14-0
(6S)-2,6-dimethyl-2-icosene

: 230966-18-4
(S)-4-methyloctadecyl tosylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) O₃, NaHCO₃; 2.) NaBH₄ / 1.) n-hexane, MeOH, CH₂Cl₂, -78 deg C, 10 h; 2.) n-hexane, MeOH, CH₂Cl₂, -78 deg C to 0 deg C, 3 h

2: 98 percent / pyridine / 12 h / 4 °C

With sodium tetrahydroborate; sodium hydrogencarbonate; ozone; In pyridine;
DOI:10.1002/(SICI)1099-0690(199905)1999:5<981::AID-EJOC981>3.0.CO;2-3

Reference yield:

: 230966-14-0
(6S)-2,6-dimethyl-2-icosene

: 230966-24-2
(10RS,13S)-13-methyl-10-phenylsulfonyl-1-(tetrahydropyran-2-yl)oxyheptacosane

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) O₃, NaHCO₃; 2.) NaBH₄ / 1.) n-hexane, MeOH, CH₂Cl₂, -78 deg C, 10 h; 2.) n-hexane, MeOH, CH₂Cl₂, -78 deg C to 0 deg C, 3 h

2: 98 percent / pyridine / 12 h / 4 °C

3: 96 percent / NaI, NaHCO₃ / acetone / 4 h / Heating

4: 87 percent / dimethylformamide / 10 h / Ambient temperature

5: 81 percent / n-BuLi / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 10 h / Ambient temperature

With sodium tetrahydroborate; n-butyllithium; sodium hydrogencarbonate; ozone; sodium iodide; In tetrahydrofuran; pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; N,N-dimethyl-formamide; acetone;
DOI:10.1002/(SICI)1099-0690(199905)1999:5<981::AID-EJOC981>3.0.CO;2-3