(4S)-S-(2',6'-anhydro-3',4',5',7'-tetra-O-benzyl-1'-deoxy-D-glycero-D-gulo-heptitol-1'-yl)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(sulfonylmethyl)-1,3-oxazolidine

Base Information

Chemical Name:(4S)-S-(2',6'-anhydro-3',4',5',7'-tetra-O-benzyl-1'-deoxy-D-glycero-D-gulo-heptitol-1'-yl)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(sulfonylmethyl)-1,3-oxazolidine
CAS No.:246864-28-8
Molecular Formula:C₄₆H₅₇NO₁₀S
Molecular Weight:816.025
Hs Code.:

(4S)-S-(2',6'-anhydro-3',4',5',7'-tetra-O-benzyl-1'-deoxy-D-glycero-D-gulo-heptitol-1'-yl)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(sulfonylmethyl)-1,3-oxazolidine

Synonyms:(4S)-S-(2',6'-anhydro-3',4',5',7'-tetra-O-benzyl-1'-deoxy-D-glycero-D-gulo-heptitol-1'-yl)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(sulfonylmethyl)-1,3-oxazolidine

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Chemical Property of (4S)-S-(2',6'-anhydro-3',4',5',7'-tetra-O-benzyl-1'-deoxy-D-glycero-D-gulo-heptitol-1'-yl)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(sulfonylmethyl)-1,3-oxazolidine

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Technology Process of (4S)-S-(2',6'-anhydro-3',4',5',7'-tetra-O-benzyl-1'-deoxy-D-glycero-D-gulo-heptitol-1'-yl)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(sulfonylmethyl)-1,3-oxazolidine

There total 8 articles about (4S)-S-(2',6'-anhydro-3',4',5',7'-tetra-O-benzyl-1'-deoxy-D-glycero-D-gulo-heptitol-1'-yl)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(sulfonylmethyl)-1,3-oxazolidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 246864-27-7
(S)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(thiomethyl)-1,3-oxazolidine

: 246864-28-8
(4S)-S-(2',6'-anhydro-3',4',5',7'-tetra-O-benzyl-1'-deoxy-D-glycero-D-gulo-heptitol-1'-yl)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(sulfonylmethyl)-1,3-oxazolidine

Guidance literature:: Multi-step reaction with 2 steps

1: 71 percent / K₂CO₃ / acetone / 4.4 h / Heating

2: mCPBA; Na₂HPO₄ / CH₂Cl₂ / 3 h

With disodium hydrogenphosphate; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; acetone;
DOI:10.1002/1099-0690(200204)2002:7<1323::AID-EJOC1323>3.0.CO;2-8

Reference yield:

: 102308-32-7
(4S)-4-formyl-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester

: 246864-28-8
(4S)-S-(2',6'-anhydro-3',4',5',7'-tetra-O-benzyl-1'-deoxy-D-glycero-D-gulo-heptitol-1'-yl)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(sulfonylmethyl)-1,3-oxazolidine

Guidance literature:: Multi-step reaction with 4 steps

1: NaBH₄

2: NaOMe

3: K₂CO₃ / acetonitrile; methanol / Heating

4: MCPBA; Na₂HPO₄

With sodium tetrahydroborate; disodium hydrogenphosphate; sodium methylate; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In methanol; acetonitrile; 1: Reduction / 2: Deacetylation / 3: Alkylation / 4: Oxidation;
DOI:10.1039/a905014k