methyl 3-(ethoxymethoxy)-2-methoxy-6-(2-methoxy-2-oxoethyl)-4-(2-(4,5,7,8,9-pentamethoxy-3-oxo-2,3-dihydronaphtho[2,3-b]furan-2-yl)ethyl)benzoate

Base Information

Chemical Name:methyl 3-(ethoxymethoxy)-2-methoxy-6-(2-methoxy-2-oxoethyl)-4-(2-(4,5,7,8,9-pentamethoxy-3-oxo-2,3-dihydronaphtho[2,3-b]furan-2-yl)ethyl)benzoate
CAS No.:1402733-59-8
Molecular Formula:C₃₄H₄₀O₁₄
Molecular Weight:672.683
Hs Code.:

Synonyms:methyl 3-(ethoxymethoxy)-2-methoxy-6-(2-methoxy-2-oxoethyl)-4-(2-(4,5,7,8,9-pentamethoxy-3-oxo-2,3-dihydronaphtho[2,3-b]furan-2-yl)ethyl)benzoate

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Chemical Property of methyl 3-(ethoxymethoxy)-2-methoxy-6-(2-methoxy-2-oxoethyl)-4-(2-(4,5,7,8,9-pentamethoxy-3-oxo-2,3-dihydronaphtho[2,3-b]furan-2-yl)ethyl)benzoate

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Technology Process of methyl 3-(ethoxymethoxy)-2-methoxy-6-(2-methoxy-2-oxoethyl)-4-(2-(4,5,7,8,9-pentamethoxy-3-oxo-2,3-dihydronaphtho[2,3-b]furan-2-yl)ethyl)benzoate

There total 12 articles about methyl 3-(ethoxymethoxy)-2-methoxy-6-(2-methoxy-2-oxoethyl)-4-(2-(4,5,7,8,9-pentamethoxy-3-oxo-2,3-dihydronaphtho[2,3-b]furan-2-yl)ethyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: (Z)-methyl 3-(ethoxymethoxy)-2-methoxy-6-(2-methoxy-2-oxoethyl)-4-(2-(4,5,7,8,9-pentamethoxy-3-oxonaphtho[2,3-b]furan-2(3H)-ylidene)ethyl)benzoate

: 1402733-59-8
methyl 3-(ethoxymethoxy)-2-methoxy-6-(2-methoxy-2-oxoethyl)-4-(2-(4,5,7,8,9-pentamethoxy-3-oxo-2,3-dihydronaphtho[2,3-b]furan-2-yl)ethyl)benzoate

Guidance literature:: With 5%-palladium/activated carbon; hydrogen; In 1,4-dioxane; methanol; for 2h; under 760.051 Torr;
DOI:10.1021/ol3024874

Reference yield:

: 1402733-48-5
methyl 4-allyl-3-hydroxy-2-methoxy-6-(2-methoxy-2-oxoethyl)benzoate

: 1402733-59-8
methyl 3-(ethoxymethoxy)-2-methoxy-6-(2-methoxy-2-oxoethyl)-4-(2-(4,5,7,8,9-pentamethoxy-3-oxo-2,3-dihydronaphtho[2,3-b]furan-2-yl)ethyl)benzoate

Guidance literature:: Multi-step reaction with 5 steps

1.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 4.5 h / 0 - 20 °C / Inert atmosphere

2.1: ozone / methanol / 1 h / -78 °C

2.2: 2 h / 20 °C

3.1: lithium diisopropyl amide / tetrahydrofuran / 1.08 h / -78 °C

3.2: 4.5 h / -78 - -40 °C

4.1: methanesulfonyl chloride; triethylamine / dichloromethane / 1 h / -78 - 0 °C

5.1: hydrogen; 5%-palladium/activated carbon / methanol; 1,4-dioxane / 2 h / 760.05 Torr

With 5%-palladium/activated carbon; hydrogen; ozone; methanesulfonyl chloride; triethylamine; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane;
DOI:10.1021/ol3024874

Reference yield:

: 1402733-49-6
methyl 4-allyl-3-(ethoxymethoxy)-2-methoxy-6-(2-methoxy-2-oxoethyl)benzoate

: 1402733-59-8
methyl 3-(ethoxymethoxy)-2-methoxy-6-(2-methoxy-2-oxoethyl)-4-(2-(4,5,7,8,9-pentamethoxy-3-oxo-2,3-dihydronaphtho[2,3-b]furan-2-yl)ethyl)benzoate

Guidance literature:: Multi-step reaction with 4 steps

1.1: ozone / methanol / 1 h / -78 °C

1.2: 2 h / 20 °C

2.1: lithium diisopropyl amide / tetrahydrofuran / 1.08 h / -78 °C

2.2: 4.5 h / -78 - -40 °C

3.1: methanesulfonyl chloride; triethylamine / dichloromethane / 1 h / -78 - 0 °C

4.1: hydrogen; 5%-palladium/activated carbon / methanol; 1,4-dioxane / 2 h / 760.05 Torr

With 5%-palladium/activated carbon; hydrogen; ozone; methanesulfonyl chloride; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane;
DOI:10.1021/ol3024874