1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane

Base Information

• Chemical Name: 1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane
• CAS No.: 1246735-85-2
• Molecular Formula: C₂₄H₃₆N₂P₂
• Molecular Weight: 414.511
• Mol file: 1246735-85-2.mol

Synonyms:1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane

Chemical Property of 1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane

There total 1 articles about 1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C6H15O2P (1571910-60-5) + aniline (62-53-3) → 1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane (1246735-85-2)

Guidance literature:

In ethanol; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1039/c3dt53268b

Reference yield: 97.0%

1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane (1246735-85-2) + [Co(1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane)(CH3CN)3]BF4 + acetonitrile (75-05-8,26809-02-9) → 1.5[Co(1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane)2]BF4*CH3CN

Guidance literature:

With Zn; In acetonitrile; (N2); std. Schlenk technique; Zn dust (23 equiv.) was added to soln. of Co complex in MeCN; stirred for 21 h; filtered; filtrate was added to ligand (1 equiv.); stirred for 45 min; evapd. (vac.); dissolved in CH2Cl2; passed through Celite; Celite rinsedwith CH2Cl2; combined filtrate concd.; hexane added; filtered; dried (v ac.);

DOI:10.1021/om200709z

Reference yield: 97.0%

[(acetonitrile)6 cobalt(II)] tetrafluoroborate + 1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane (1246735-85-2) → Co(C6H5N(CH2P(C(CH3)3)CH2)2NC6H5)(NCCH3)3(2+)*2BF4(1-)=[Co(C6H5N(CH2P(C(CH3)3)CH2)2NC6H5)(NCCH3)3][BF4]2

Guidance literature:

In acetonitrile; under N2; soln. of Co complex in MeCN added to suspn. of P2N2-octacycle in MeCN, mixt. stirred for 24 h; concn. under vac., crystn. by vapor diffusion of Et2O into soln.; elem. anal.;

DOI:10.1021/om100395r

upstream raw materials:

C₆H₁₅O₂P

aniline

Downstream raw materials:

[Ni(1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane)2]BF₄

[Ni(1,5-phenyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane)2]

[Fe(μ-1,2-benzenedithiolate)(C24H36N2P2)(CO)]