Technology Process of C12H10O5
There total 1 articles about C12H10O5 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
N-ethyl-N,N-diisopropylamine;
In
N,N-dimethyl-formamide;
at 20 ℃;
for 6h;
DOI:10.1021/ol991067y
- Guidance literature:
-
Multi-step reaction with 6 steps
1: NEt3 / tetrahydrofuran
2: diethyl ether / 24 h / -15 - -5 °C
3: 74 percent / Rh2(OAc)4 / CH2Cl2 / 5 h / 20 °C
4: 93 percent / aq. HCl / dioxane / 3 h / 20 °C
5: 68 percent / NaH / dimethylformamide / 50 °C
6: 150 °C
With
sodium hydride; triethylamine;
hydrogenchloride; dirhodium tetraacetate;
In
tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
6: retro-hetero Diels-Alder reaction;
DOI:10.1021/ol991067y
- Guidance literature:
-
Multi-step reaction with 7 steps
1: NEt3 / tetrahydrofuran
2: diethyl ether / 24 h / -15 - -5 °C
3: 74 percent / Rh2(OAc)4 / CH2Cl2 / 5 h / 20 °C
4: 93 percent / aq. HCl / dioxane / 3 h / 20 °C
5: 68 percent / NaH / dimethylformamide / 50 °C
6: 150 °C
7: 24 h / 150 °C
With
sodium hydride; triethylamine;
hydrogenchloride; dirhodium tetraacetate;
In
tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
6: retro-hetero Diels-Alder reaction / 7: hetero Diels-Alder reaction;
DOI:10.1021/ol991067y