N'-[2,3-bis-(dimethyl-vinyl-silanyloxy)-propylidene]-N,N-diphenyl-hydrazine

Base Information

• Chemical Name: N'-[2,3-bis-(dimethyl-vinyl-silanyloxy)-propylidene]-N,N-diphenyl-hydrazine
• CAS No.: 324753-68-6
• Molecular Formula: C₂₃H₃₂N₂O₂Si₂
• Molecular Weight: 424.69
• Mol file: 324753-68-6.mol

Synonyms:N'-[2,3-bis-(dimethyl-vinyl-silanyloxy)-propylidene]-N,N-diphenyl-hydrazine

Chemical Property of N'-[2,3-bis-(dimethyl-vinyl-silanyloxy)-propylidene]-N,N-diphenyl-hydrazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N'-[2,3-bis-(dimethyl-vinyl-silanyloxy)-propylidene]-N,N-diphenyl-hydrazine

There total 2 articles about N'-[2,3-bis-(dimethyl-vinyl-silanyloxy)-propylidene]-N,N-diphenyl-hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

Chlorodimethylvinylsilane (1719-58-0) + D-glyceraldehyde N,N-diphenylhydrazone (324753-67-5) → N'-[2,3-bis-(dimethyl-vinyl-silanyloxy)-propylidene]-N,N-diphenyl-hydrazine (324753-68-6)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 5h;

DOI:10.1021/ol0067991

Reference yield:

N,N-diphenylhydrazine hydrochloride (530-47-2,29666-92-0) → N'-[2,3-bis-(dimethyl-vinyl-silanyloxy)-propylidene]-N,N-diphenyl-hydrazine (324753-68-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 43 percent / Na₂SO₄ / H₂O; toluene / 48 h / 20 °C

2: 70 percent / triethylamine / CH₂Cl₂ / 5 h / 0 - 20 °C

With sodium sulfate; triethylamine; In dichloromethane; water; toluene;

DOI:10.1021/ol0067991

Reference yield:

N'-[2,3-bis-(dimethyl-vinyl-silanyloxy)-propylidene]-N,N-diphenyl-hydrazine (324753-68-6) → 3-(N',N'-diphenyl-hydrazino)-pent-4-ene-1,2-diol

Guidance literature:

N'-[2,3-bis-(dimethyl-vinyl-silanyloxy)-propylidene]-N,N-diphenyl-hydrazine; With 2,2'-azobis(isobutyronitrile); thiophenol; In cyclohexane; Heating;

With potassium fluoride; In tetrahydrofuran; methanol; at 20 ℃; for 20h; Further stages.;

DOI:10.1021/ol0067991

upstream raw materials:

Chlorodimethylvinylsilane

D-glyceraldehyde N,N-diphenylhydrazone

N,N-diphenylhydrazine hydrochloride