2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexos-2-ulo-2,5-furanose

Base Information

• Chemical Name: 2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexos-2-ulo-2,5-furanose
• CAS No.: 145121-60-4
• Molecular Formula: C₁₉H₂₄O₅
• Molecular Weight: 332.397
• Mol file: 145121-60-4.mol

Synonyms:2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexos-2-ulo-2,5-furanose

Chemical Property of 2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexos-2-ulo-2,5-furanose

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexos-2-ulo-2,5-furanose

There total 1 articles about 2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexos-2-ulo-2,5-furanose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-psicofuranose (145121-59-1) → 2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexos-2-ulo-2,5-furanose (145121-60-4)

Guidance literature:

With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -60 ℃; for 0.25h;

DOI:10.1016/0040-4020(94)01027-W

Reference yield: 67.0%

2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexos-2-ulo-2,5-furanose (145121-60-4) → 2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexulofuranosonic acid

Guidance literature:

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; In water; tert-butyl alcohol; for 0.5h; Ambient temperature;

DOI:10.1016/0040-4020(94)01027-W

Reference yield:

2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexos-2-ulo-2,5-furanose (145121-60-4) → 2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexulofuranosonamide

Guidance literature:

With ammonia; In tetrahydrofuran; at 0 ℃; for 0.5h; Yield given;

DOI:10.1016/0040-4020(94)01027-W

upstream raw materials:

2-allyl-6-O-benzyl-2-deoxy-3,4-O-isopropylidene-β-D-psicofuranose