methyl (E)-3-(tert-butyldimethylsilyloxy)-2-diazo-4-(4-methoxyphenyl)but-3-enoate

Base Information

Chemical Name:methyl (E)-3-(tert-butyldimethylsilyloxy)-2-diazo-4-(4-methoxyphenyl)but-3-enoate
CAS No.:1393642-68-6
Molecular Formula:C₁₈H₂₆N₂O₄Si
Molecular Weight:362.501
Hs Code.:

Synonyms:methyl (E)-3-(tert-butyldimethylsilyloxy)-2-diazo-4-(4-methoxyphenyl)but-3-enoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (E)-3-(tert-butyldimethylsilyloxy)-2-diazo-4-(4-methoxyphenyl)but-3-enoate

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Technology Process of methyl (E)-3-(tert-butyldimethylsilyloxy)-2-diazo-4-(4-methoxyphenyl)but-3-enoate

There total 1 articles about methyl (E)-3-(tert-butyldimethylsilyloxy)-2-diazo-4-(4-methoxyphenyl)but-3-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1393642-87-9
methyl 2-diazo-4-(4-methoxyphenyl)-3-oxobutanoate

: 69739-34-0
t-butyldimethylsiyl triflate

: 1393642-67-5
methyl (Z)-3-(tert-butyldimethylsilyloxy)-2-diazo-4-(4-methoxyphenyl)but-3-enoate

: 1393642-68-6
methyl (E)-3-(tert-butyldimethylsilyloxy)-2-diazo-4-(4-methoxyphenyl)but-3-enoate

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃; for 0.333333h; optical yield given as %de; Inert atmosphere;
DOI:10.1002/anie.201202525

Reference yield: 82.0%

: 1393642-68-6
methyl (E)-3-(tert-butyldimethylsilyloxy)-2-diazo-4-(4-methoxyphenyl)but-3-enoate

: 1137-96-8,26505-49-7,201024-81-9
N-(benzylidene)aniline N-oxide

: methyl 5-(tert-butyldimethylsilyloxy)-6-(4-methoxyphenyl)-2,3-diphenyl-3,6-dihydro-2H-1,2-oxazine-4-carboxylate

Guidance literature:: With copper(II) hexafluoroantimonate; benzyl alcohol; In dichloromethane; at 20 ℃; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.201202525