(2S,3S,4R,5S,6R)-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl tetrahydro-2H-pyran-2-carbaldehyde

Base Information

Chemical Name:(2S,3S,4R,5S,6R)-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl tetrahydro-2H-pyran-2-carbaldehyde
CAS No.:1054608-34-2
Molecular Formula:C₃₂H₅₈O₈Si₂
Molecular Weight:626.979
Hs Code.:

(2S,3S,4R,5S,6R)-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl tetrahydro-2H-pyran-2-carbaldehyde

Synonyms:(2S,3S,4R,5S,6R)-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl tetrahydro-2H-pyran-2-carbaldehyde

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Chemical Property of (2S,3S,4R,5S,6R)-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl tetrahydro-2H-pyran-2-carbaldehyde

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Technology Process of (2S,3S,4R,5S,6R)-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl tetrahydro-2H-pyran-2-carbaldehyde

There total 1 articles about (2S,3S,4R,5S,6R)-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl tetrahydro-2H-pyran-2-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1054608-67-1
(2S,3S,4R,5S,6R)-methyl-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyltetrahydro-2H-pyran-2-carboxylate

: 1054608-34-2
(2S,3S,4R,5S,6R)-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl tetrahydro-2H-pyran-2-carbaldehyde

Guidance literature:: (2S,3S,4R,5S,6R)-methyl-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyltetrahydro-2H-pyran-2-carboxylate; With diisobutylaluminium hydride; In diethyl ether; hexane; at -78 ℃; Inert atmosphere;

With rochelle salt; In diethyl ether;
DOI:10.1021/ol801499s

Reference yield: 81.0%

: (R)-3-(benzyloxy-2-methyl-propyl)-triphenyl-phosphonium bromide

: 1054608-34-2
(2S,3S,4R,5S,6R)-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl tetrahydro-2H-pyran-2-carbaldehyde

: 1054608-68-2
(2-((2S,3S,4R,5S,6R)-6-((S,Z)-4-(benzyloxy)-3-methylbut-1-enyl)-4-(tert-butyldimethylsilyloxy)-3,5-dimethyltetrahydro-2H-pyran-2-yl)-4,6-dimethoxy-3-((methoxymethoxy)methyl)-5-methylphenoxy)(tert-butyl)dimethylsilane

: C₄₃H₇₂O₈Si₂

Guidance literature:: (R)-3-(benzyloxy-2-methyl-propyl)-triphenyl-phosphonium bromide; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; Inert atmosphere;

(2S,3S,4R,5S,6R)-4-(tert-butyldimethylsilyloxy)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl tetrahydro-2H-pyran-2-carbaldehyde; With water; In tetrahydrofuran; optical yield given as %de; Inert atmosphere;
DOI:10.1021/ol801499s