{3-allyloxy-4-[2-(3,8,13-trimethoxy-7,12-bis-{2-[2-methoxy-4-(tetrahydro-pyran-2-yloxymethyl)-phenoxy]-ethoxy}-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy)-ethoxy]-phenyl}-methanol

Base Information

Chemical Name:{3-allyloxy-4-[2-(3,8,13-trimethoxy-7,12-bis-{2-[2-methoxy-4-(tetrahydro-pyran-2-yloxymethyl)-phenoxy]-ethoxy}-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy)-ethoxy]-phenyl}-methanol
CAS No.:391895-30-0
Molecular Formula:C₆₆H₇₈O₁₇
Molecular Weight:1143.34
Hs Code.:

{3-allyloxy-4-[2-(3,8,13-trimethoxy-7,12-bis-{2-[2-methoxy-4-(tetrahydro-pyran-2-yloxymethyl)-phenoxy]-ethoxy}-10,15-dihydro-5<i>H</i>-tribenzo[<i>a</i>,<i>d</i>,<i>g</i>]cyclononen-2-yloxy)-ethoxy]-phenyl}-methanol

Synonyms:{3-allyloxy-4-[2-(3,8,13-trimethoxy-7,12-bis-{2-[2-methoxy-4-(tetrahydro-pyran-2-yloxymethyl)-phenoxy]-ethoxy}-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy)-ethoxy]-phenyl}-methanol

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Chemical Property of {3-allyloxy-4-[2-(3,8,13-trimethoxy-7,12-bis-{2-[2-methoxy-4-(tetrahydro-pyran-2-yloxymethyl)-phenoxy]-ethoxy}-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy)-ethoxy]-phenyl}-methanol

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Technology Process of {3-allyloxy-4-[2-(3,8,13-trimethoxy-7,12-bis-{2-[2-methoxy-4-(tetrahydro-pyran-2-yloxymethyl)-phenoxy]-ethoxy}-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy)-ethoxy]-phenyl}-methanol

There total 10 articles about {3-allyloxy-4-[2-(3,8,13-trimethoxy-7,12-bis-{2-[2-methoxy-4-(tetrahydro-pyran-2-yloxymethyl)-phenoxy]-ethoxy}-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy)-ethoxy]-phenyl}-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 710338-34-4
4-(2-bromoethoxy)-3-(2-propen-1-yloxy)benzenemethanol

: 811867-93-3
3,8,13-trimethoxy-7,12-bis-{2-[2-methoxy-4-(tetrahydro-pyran-2-yloxymethyl)-phenoxy]-ethoxy}-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-ol

: 391895-30-0
{3-allyloxy-4-[2-(3,8,13-trimethoxy-7,12-bis-{2-[2-methoxy-4-(tetrahydro-pyran-2-yloxymethyl)-phenoxy]-ethoxy}-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy)-ethoxy]-phenyl}-methanol

Guidance literature:: With potassium peroxomonocarbonate; tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide; at 80 ℃; for 8h;
DOI:10.1021/ja0483037

Reference yield: 80.0%

: 347894-43-3
2-[4-(2-iodoethoxy)-3-methoxybenzyloxy]-tetrahydropyran

: 426821-82-1
12-[2-(2-allyloxy-4-hydroxymethyl-phenoxy)-ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene-2,7-diol

: 391895-30-0
{3-allyloxy-4-[2-(3,8,13-trimethoxy-7,12-bis-{2-[2-methoxy-4-(tetrahydro-pyran-2-yloxymethyl)-phenoxy]-ethoxy}-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy)-ethoxy]-phenyl}-methanol

Guidance literature:: With caesium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 18h;
DOI:10.1039/b109301k

Reference yield:

: 81370-49-2,68198-62-9,75322-24-6,68182-93-4
cyclotriguaiacyclene

: 391895-30-0
{3-allyloxy-4-[2-(3,8,13-trimethoxy-7,12-bis-{2-[2-methoxy-4-(tetrahydro-pyran-2-yloxymethyl)-phenoxy]-ethoxy}-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy)-ethoxy]-phenyl}-methanol

Guidance literature:: Multi-step reaction with 4 steps

1: 67 percent Turnov_. / Cs₂CO₃ / dimethylformamide / 2 h / 80 °C

2: 81 percent / K₂CO₃; n-Bu₄NI / dimethylformamide / 8 h / 80 °C

3: 89 percent / Pd(PPh₃)4; n-Bu₃SnH / CH₂Cl₂ / 1.5 h / 23 °C

4: 84 percent / K₂CO₄; n-Bu₄NI / dimethylformamide / 8 h / 80 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium peroxomonocarbonate; tri-n-butyl-tin hydride; tetra-(n-butyl)ammonium iodide; potassium carbonate; caesium carbonate; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja0483037