(1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid (R)-(+)-α-methylbenzammonium salt

Base Information

Chemical Name:(1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid (R)-(+)-α-methylbenzammonium salt
CAS No.:148082-88-6
Molecular Formula:C₆H₆O₄*C₈H₁₁N
Molecular Weight:263.293
Hs Code.:

Synonyms:(1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid (R)-(+)-α-methylbenzammonium salt

Suppliers and Price of (1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid (R)-(+)-α-methylbenzammonium salt

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of (1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid (R)-(+)-α-methylbenzammonium salt

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid (R)-(+)-α-methylbenzammonium salt

There total 1 articles about (1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid (R)-(+)-α-methylbenzammonium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.89%

: 3886-69-9
(R)-1-phenyl-ethyl-amine

: 499-02-5
Feist's acid

: 148152-70-9
(1S,2S)-(-)-3-methylenecyclopropane-1,2-dicarboxylic acid (R)-(+)-α-methylbenzammonium salt

: 148082-88-6
(1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid (R)-(+)-α-methylbenzammonium salt

Guidance literature:: In water; tert-butyl alcohol; at 20 ℃; for 24.5h;
DOI:10.3390/molecules17055550

Reference yield:

: 148082-88-6
(1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid (R)-(+)-α-methylbenzammonium salt

: 499-02-5,45786-15-0,139891-18-2,148152-68-5,75880-66-9
(1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid

Guidance literature:: With sulfuric acid; In water; ethyl acetate; for 0.0833333h;
DOI:10.3390/molecules17055550

Reference yield:

: 148082-88-6
(1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid (R)-(+)-α-methylbenzammonium salt

: 1391950-67-6
(1R,2R)-N₁,N₂-benzyl-3-methylenecyclopropane-1,2-dicarboxamide

Guidance literature:: Multi-step reaction with 3 steps

1: sulfuric acid / water; ethyl acetate / 0.08 h

2: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 1 h / 20 °C / Inert atmosphere

3: N-ethyl-N,N-diisopropylamine / dichloromethane / 3 h / 20 °C / Inert atmosphere

With oxalyl dichloride; sulfuric acid; N-ethyl-N,N-diisopropylamine; N,N-dimethyl-formamide; In dichloromethane; water; ethyl acetate;
DOI:10.3390/molecules17055550