NAPHTHALENE-1,4-D2

Base Information

• Chemical Name: NAPHTHALENE-1,4-D2
• CAS No.: 1683-98-3
• Molecular Formula: C10H6 D2
• Molecular Weight: 130.158
• Mol file: 1683-98-3.mol

Synonyms:NAPHTHALENE-1,4-D2

Chemical Property of NAPHTHALENE-1,4-D2

Chemical Property:

• PSA: 0.00000
• LogP: 2.83980

Purity/Quality:

99% ^*data from raw suppliers

NAPHTHALENE-1,4-D2 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of NAPHTHALENE-1,4-D2

There total 5 articles about NAPHTHALENE-1,4-D2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

cis-1,4-dideuterio-1,4-dihydro-1-methoxynaphthalene (101916-88-5) → naphthalene (91-20-3,71998-51-1,72931-45-4) + 1-deuteronaphthalene (875-62-7) + 1,4-dideuterionaphthalene (1683-98-3)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; for 0.5h; Product distribution; other solvents, bases;

DOI:10.1021/jo00361a011

Reference yield:

cis/trans-<1,4-D2>-1,4-Dihydronaphthalin (134567-85-4,104977-10-8) → naphthalene (91-20-3,71998-51-1,72931-45-4) + 1-deuteronaphthalene (875-62-7) + 1,4-dideuterionaphthalene (1683-98-3)

Guidance literature:

In 1,4-dioxane; at 25 ℃; Mechanism; Product distribution; var. of solvent, reagent;

Reference yield:

cis-<1,4-D2>-1,4-Dihydronaphthalin (104977-13-1,104977-10-8) → naphthalene (91-20-3,71998-51-1,72931-45-4) + 1-deuteronaphthalene (875-62-7) + 1,4-dideuterionaphthalene (1683-98-3)

Guidance literature:

In 1,4-dioxane; at 25 ℃; Mechanism; Product distribution; var. of solvent, reagent;

upstream raw materials:

cis/trans-<1,4-D2>-1,4-Dihydronaphthalin

cis-1,4-dideuterio-1,4-dihydro-1-methoxynaphthalene

cis-<1,4-D2>-1,4-Dihydronaphthalin

<1,1,4,4-D4>-1,4-Dihydronaphthalin

Downstream raw materials:

[1,4]naphthoquinone

Refernces

• 1、 Pawliczek,Guenther. "". . p. 1755,1757,1758,1767,1768. Retrieved 1970.
• 2、 Brock, Martin,Hintze, Horst,Heesing, Albert. "Hydrogen Transfer Reactions, 10. The cis-Selective Two-Step Mechanism in Hydrogen Transfer from 1,4-Dihydroarenes to o- and p-Quinones". . p. 3727 - 3736. Retrieved 2007/10/02.