bis[di(p-tolyl)(μ-diethyl sulfide)platinum(II)]

Base Information

Chemical Name:bis[di(p-tolyl)(μ-diethyl sulfide)platinum(II)]
CAS No.:64827-19-6
Molecular Formula:C₃₆H₄₈Pt₂S₂
Molecular Weight:935.069
Hs Code.:

Synonyms:bis[di(p-tolyl)(μ-diethyl sulfide)platinum(II)]

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Chemical Property of bis[di(p-tolyl)(μ-diethyl sulfide)platinum(II)]

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Technology Process of bis[di(p-tolyl)(μ-diethyl sulfide)platinum(II)]

There total 1 articles about bis[di(p-tolyl)(μ-diethyl sulfide)platinum(II)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 14873-92-8
dichlorobis(diethyl sulfide)platinum

: 2417-95-0
p-tolyllithium

: 64827-19-6
bis[di(p-tolyl)(μ-diethyl sulfide)platinum(II)]

Guidance literature:: In diethyl ether; toluene; under N2; adding solid PtCl2(SEt2)2 to soln. of Li(p-Tol) in Et2O and toluene at -78°C, stirring for 3 h at this temp. and then for 4 h at ambient temp., adding water; removal of volatiles in vac., extn. of mixt. with CH2Cl2, drying combined org. fraction over MgSO4, filtration, evapn. under reduced pressure, recrystn. from acetone;

Reference yield: 98.0%

: 1042420-05-2
HON=CH-4-C₆H₂(CH₂NMe₂)2-2,6-Br-1

: 64827-19-6
bis[di(p-tolyl)(μ-diethyl sulfide)platinum(II)]

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: [(HON=CH-4-C₆H₂(CH₂NMe₂)2-2,6)PtBr]*1/3(benzene)

Guidance literature:: In benzene; under N2 atm. soln. Pt complex and ligand in benzene was refluxed for 5 min; soln. was cooled to room temp. and concd. in vacuo, n-hexane was added, ppt. was collected and washed with n-hexane and Et2O, vac.-dried; elem. anal.;
DOI:10.1016/j.jorganchem.2008.03.020

Reference yield: 89.0%

: 64827-19-6
bis[di(p-tolyl)(μ-diethyl sulfide)platinum(II)]

: potassium tris(1-pyrazolyl)borate

: K⁽¹⁺⁾*Pt(C₆H₄CH₃)2((C₃H₃N₂)3BH)^(1-)=K[Pt(C₆H₄CH₃)2((C₃H₃N₂)3BH)]

Guidance literature:: In tetrahydrofuran; N2-atmosphere; stirring (1.5 h); evapn. (vac.), extg. (THF / Et2O = 1 : 2), filtering, evapn., pptn. on pentane addn.; elem. anal.;