[Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate)

Base Information

• Chemical Name: [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate)
• CAS No.: 1008133-51-4
• Molecular Formula: C₄₁H₃₁BrIrN₄*F₆P
• Molecular Weight: 996.812

Synonyms:[Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate)

Chemical Property of [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate)

There total 1 articles about [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

potassium hexafluorophosphate (17084-13-8) + bis(μ-chloro)-bis[1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C(2'),N-iridium chloride] + 4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine (1008133-62-7) → [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C2,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate) (1008133-51-4) + [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C2,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate)

Guidance literature:

With silver trifluoromethanesulfonate; In ethylene glycol; byproducts: AgCl; stirring suspn. of iridium compd., bipyridine deriv. and silver compd. in ethylene glycol at room temp. for 1 h under N2, heating at 196°C for 2 h; cooling to room temp., centrifugation, extn. (CH3CN) from ppt., concg. combined organic solns., addn. to satd. aq. soln. of KPF6, centrifugation, washing with water, drying in vac., chromy. (silica, CH2Cl2/methanol from 100/0 to 98.75/1.25), elem. anal.;

DOI:10.1021/ic701788d

Reference yield: 72.0%

[Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C2,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate) (1008133-51-4) + phenylboronic acid (98-80-6) → [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C2,N)(mtbpy-.vphi.-Ph)](hexafluorophosphate) (1008133-53-6)

Guidance literature:

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In water; dimethyl sulfoxide; byproducts: Pd; degassing mixt. of iridium compd., phenylboronic acid in DMSO and aq. soln. of Na2CO3 under N2, addn. of palladium compd., stirring for 18 h under N2 at 80°; cooling to room temp., addn. of CH3CN, filtration, addn. of filtrate to satd. aq. soln. of KPF6, centrifugation, washing with water, drying in vac., chromy. (silica, CH2Cl2/methanol from 100/0 to 99/1), elem. anal.;

DOI:10.1021/ic701788d

upstream raw materials:

potassium hexafluorophosphate

4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine

Downstream raw materials:

[Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(mtbpy-.vphi.-Ph)](hexafluorophosphate)

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1008133-51-4 [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate)

Send

Send

Metric Ton KG G Pound L ML

Send

Send