Technology Process of C32H46O6Si
There total 24 articles about C32H46O6Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium carbonate;
In
tetrahydrofuran; methanol;
DOI:10.1021/ja9824932
- Guidance literature:
-
With
hydrogenchloride;
In
acetone;
at 20 ℃;
for 0.5h;
DOI:10.1021/ja9939439
- Guidance literature:
-
Multi-step reaction with 7 steps
1: 66 percent / diethyl zinc / toluene; hexane / 0.5 h / 0 °C
2: 77 percent / Dess-Martin periodinane / CH2Cl2 / 12 h / 20 °C
3: 84 percent / H2 / Pd(OH)2 / ethanol / 0.5 h / 20 °C
4: pyridine / CH2Cl2 / 2 h / -45 °C
5: 0.742 g / TBAF; AcOH / tetrahydrofuran / 2.5 h / 20 °C
6: 86 percent / pyridinium p-toluenesulfonate / benzene / 1 h / Heating
7: 100 percent / K2CO3 / tetrahydrofuran; methanol / 1 h / 20 °C
With
pyridine; tetrabutyl ammonium fluoride; hydrogen; diethylzinc; pyridinium p-toluenesulfonate; potassium carbonate; Dess-Martin periodane; acetic acid;
palladium dihydroxide;
In
tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; toluene; benzene;
1: Cycloaddition / 2: Dess-Martin oxidation / 3: Hydrogenolysis / 4: cyclocondensation / 5: desilylation / 6: cyclocondensation / 7: Ring cleavage;
DOI:10.1021/ja9939439