(2R,3R)-3-Benzyloxy-2,4-bis-(tert-butyl-dimethyl-silanyloxy)-butyraldehyde

Base Information

Chemical Name:(2R,3R)-3-Benzyloxy-2,4-bis-(tert-butyl-dimethyl-silanyloxy)-butyraldehyde
CAS No.:855127-43-4
Molecular Formula:C₂₃H₄₂O₄Si₂
Molecular Weight:438.755
Hs Code.:

Synonyms:(2R,3R)-3-Benzyloxy-2,4-bis-(tert-butyl-dimethyl-silanyloxy)-butyraldehyde

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Chemical Property of (2R,3R)-3-Benzyloxy-2,4-bis-(tert-butyl-dimethyl-silanyloxy)-butyraldehyde

Chemical Property:

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Technology Process of (2R,3R)-3-Benzyloxy-2,4-bis-(tert-butyl-dimethyl-silanyloxy)-butyraldehyde

There total 5 articles about (2R,3R)-3-Benzyloxy-2,4-bis-(tert-butyl-dimethyl-silanyloxy)-butyraldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (3S,4R)-4-Benzyloxy-3,5-bis-(tert-butyl-dimethyl-silanyloxy)-pentane-1,2-diol

: 855127-43-4
(2R,3R)-3-Benzyloxy-2,4-bis-(tert-butyl-dimethyl-silanyloxy)-butyraldehyde

Guidance literature:: With sodium periodate; In tetrahydrofuran; water; at -10 - 20 ℃;
DOI:10.1021/ol050653q

Reference yield:

: 855127-45-6
(2R,3S)-2-Benzyloxy-pent-4-ene-1,3-diol

: 855127-43-4
(2R,3R)-3-Benzyloxy-2,4-bis-(tert-butyl-dimethyl-silanyloxy)-butyraldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide / 12 h / 20 °C

2: 100 percent / K₂OsO₄*H₂O; NMO / acetone; H₂O / 48 h / 20 °C

3: 74 percent Turnov_. / NaIO₄ / tetrahydrofuran; H₂O / -10 - 20 °C

With 1H-imidazole; potassium osmate(VI); sodium periodate; N-methyl-2-indolinone; In tetrahydrofuran; water; N,N-dimethyl-formamide; acetone;
DOI:10.1021/ol050653q

Reference yield:

: (2R,4S,5R)-5-Benzyloxy-2-phenyl-4-vinyl-[1,3]dioxane

: 855127-43-4
(2R,3R)-3-Benzyloxy-2,4-bis-(tert-butyl-dimethyl-silanyloxy)-butyraldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: 2.39 g / TsOH*H₂O / methanol; CH₂Cl₂ / 7 h / 20 °C

2: imidazole / dimethylformamide / 12 h / 20 °C

3: 100 percent / K₂OsO₄*H₂O; NMO / acetone; H₂O / 48 h / 20 °C

4: 74 percent Turnov_. / NaIO₄ / tetrahydrofuran; H₂O / -10 - 20 °C

With 1H-imidazole; potassium osmate(VI); sodium periodate; N-methyl-2-indolinone; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1021/ol050653q