Methyl (2S)-2--5-hydroxy-3-pentenoate

Base Information

Chemical Name:Methyl (2S)-2--5-hydroxy-3-pentenoate
CAS No.:152389-39-4
Molecular Formula:C₂₅H₂₃NO₃
Molecular Weight:385.463
Hs Code.:

Methyl (2S)-2-<N-(9'-phenylfluoren-9'-yl)amino>-5-hydroxy-3-pentenoate

Synonyms:Methyl (2S)-2--5-hydroxy-3-pentenoate

Suppliers and Price of Methyl (2S)-2--5-hydroxy-3-pentenoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methyl (2S)-2--5-hydroxy-3-pentenoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methyl (2S)-2--5-hydroxy-3-pentenoate

There total 3 articles about Methyl (2S)-2--5-hydroxy-3-pentenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 152389-36-1
Dimethyl N-(9-phenylfluoren-9-yl)-3,4-didehydroglutamate

: 152389-39-4
Methyl (2S)-2--5-hydroxy-3-pentenoate

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; hexane; at -40 ℃; for 2.5h;
DOI:10.1021/jo00077a015

Reference yield:

: (S)-2-(9-Phenyl-9H-fluoren-9-ylamino)-pentanedioic acid dimethyl ester

: 152389-39-4
Methyl (2S)-2--5-hydroxy-3-pentenoate

Guidance literature:: Multi-step reaction with 3 steps

1: KHMDS / tetrahydrofuran / 1.) -78 deg C, 1.5 h, 2.) -78 deg C, 2 h

2: K₃PO₄, MCPBA / CH₂Cl₂ / -20 °C

3: 86 percent / DIBAL / tetrahydrofuran; hexane / 2.5 h / -40 °C

With potassium phosphate; potassium hexamethylsilazane; diisobutylaluminium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo00077a015

Reference yield:

: (S)-2-(9-Phenyl-9H-fluoren-9-ylamino)-4-phenylselanyl-pentanedioic acid dimethyl ester

: 152389-39-4
Methyl (2S)-2--5-hydroxy-3-pentenoate

Guidance literature:: Multi-step reaction with 2 steps

1: K₃PO₄, MCPBA / CH₂Cl₂ / -20 °C

2: 86 percent / DIBAL / tetrahydrofuran; hexane / 2.5 h / -40 °C

With potassium phosphate; diisobutylaluminium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo00077a015