3-Hydroxybenzaldehyde 2,4-dinitrophenylhydrazone

Base Information

• Chemical Name: 3-Hydroxybenzaldehyde 2,4-dinitrophenylhydrazone
• CAS No.: 1160-77-6
• Molecular Formula: C13H10 N4 O5
• Molecular Weight: 302.246
• Hs Code.: 2928000090
• DSSTox Substance ID: DTXSID00430540
• Mol file: 1160-77-6.mol

Synonyms:3-Hydroxybenzaldehyde 2,4-dinitrophenylhydrazone;1160-77-6;3-[(E)-[(2,4-dinitrophenyl)hydrazinylidene]methyl]phenol;Benzaldehyde, m-hydroxy-, (2,4-dinitrophenyl)hydrazone;Benzaldehyde, 3-hydroxy-, (2,4-dinitrophenyl)hydrazone;DTXSID00430540;NFICGVFXASYDJR-RIYZIHGNSA-N;AKOS003408931;m-Hydroxybenzaldehyde (2,4-dinitrophenyl)hydrazone;3-[2-(2,4-dinitrophenyl)carbonohydrazonoyl]phenol;3-Hydroxybenzaldehyde (2,4-dinitrophenyl)hydrazone #;Z49555057

Chemical Property of 3-Hydroxybenzaldehyde 2,4-dinitrophenylhydrazone

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.671
• Boiling Point: 526.2°Cat760mmHg
• Flash Point: 272°C
• PSA: 136.26000
• Density: 1.49g/cm³
• LogP: 3.77400
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 3
• Exact Mass: 302.06511943
• Heavy Atom Count: 22
• Complexity: 433

Purity/Quality:

98%,99%, ^*data from raw suppliers

3-HYDROXYBENZALDEHYDE 2,4-DINITROPHENYLHYDRAZONE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC(=C1)O)C=NNC2=C(C=C(C=C2)[N+](=O)[O-])[N+](=O)[O-]
• Isomeric SMILES: C1=CC(=CC(=C1)O)/C=N/NC2=C(C=C(C=C2)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of 3-Hydroxybenzaldehyde 2,4-dinitrophenylhydrazone

There total 3 articles about 3-Hydroxybenzaldehyde 2,4-dinitrophenylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

meta-hydroxybenzaldehyde (100-83-4) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → N-(2,4-dinitrophenyl)-N'-(3'-hydroxybenzylidene)hydrazone (1160-77-6)

Guidance literature:

With acetic acid; In methanol; Reflux;

Reference yield:

1-chloro-2,4-dinitro-benzene (97-00-7) → N-(2,4-dinitrophenyl)-N'-(3'-hydroxybenzylidene)hydrazone (1160-77-6)

Guidance literature:

Multi-step reaction with 2 steps

1: aq.-ethanolic ammonia; hydrazine hydrate

With ammonium hydroxide; hydrazine hydrate;

DOI:10.1039/jr9310000756

Reference yield:

→ N-(2,4-dinitrophenyl)-N'-(3'-hydroxybenzylidene)hydrazone (1160-77-6)

Guidance literature:

m-Hydroxy-benzaldehyd, 2,4-Dinitrophenylhydrazin;

upstream raw materials:

meta-hydroxybenzaldehyde

(2,4-dinitro-phenyl)-hydrazine

1-chloro-2,4-dinitro-benzene

Downstream raw materials:

meta-hydroxybenzaldehyde

3-[(2,4-Dinitro-phenylazo)-(triphenyl-λ⁵-phosphanylidene)-methyl]-phenol

(2,4-dinitro-phenyl)-hydrazine

C₁₃H₉BrN₄O₅

Refernces

• 1、 Anand, Siddeswaran,Dineshkumar, Sengottuvelu,Muthusamy, Athianna. "Synthesis, characterization, electrical and thermal properties of hydrazone polymers derived from 2,4–dinitro phenyl hydrazine". . . Retrieved 2021/09/22.
• 2、 Ahad, Ghulam,Khan, Momin,Khan, Asif,Ibrahim, Mohammad,Salar, Uzma,Kanwal,Khan, Khalid Mohammed,Perveen, Shahnaz. "Synthesis, structural characterization, and antioxidant activities of 2,4-dinitrophenyl-hydrazone derivatives". . p. 961 - 973. Retrieved 2018/10/02.