Tetraethyldialuminoxane

Base Information

Chemical Name:Tetraethyldialuminoxane
CAS No.:1069-83-6
Molecular Formula:C8H20 Al2 O
Molecular Weight:186.209
Hs Code.:
DSSTox Substance ID:DTXSID70586826
Wikidata:Q82479035
Mol file:1069-83-6.mol

Synonyms:TETRAETHYLDIALUMINOXANE;1069-83-6;diethylalumanyloxy(diethyl)alumane;tetraethylaluminoxane;SCHEMBL202705;DTXSID70586826

Suppliers and Price of Tetraethyldialuminoxane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Tetraethyldialuminoxane solution 1.0M in toluene
100ml
$ 270.00

Total 8 raw suppliers

Chemical Property of Tetraethyldialuminoxane

Chemical Property:

Boiling Point:111 °C
PSA：9.23000
Density:0.86 g/mL at 25 °C
LogP:3.82720
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:6
Exact Mass:186.114492
Heavy Atom Count:11
Complexity:70.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetraethyldialuminoxane solution 1.0M in toluene ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,T
Statements: 14-17-23/24/25
Safety Statements: 16-26-28-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC[Al](CC)O[Al](CC)CC

Technology Process of Tetraethyldialuminoxane

There total 13 articles about Tetraethyldialuminoxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6689-15-2
methylenebis(diethylalane)

: 98-53-3
4-tercbutyl-cyclohexanone

: 1069-83-6
tetraethylaluminoxane

Guidance literature:: In benzene; byproducts: cis-4-t-butylcyclohexanol, trans-4-t-butylcyclohexanol; ketone adding to a soln. of Al deriv. in molar ratio 1:1, stirring for 24 h; organic products analyzed by GLC after hydrolysis;
DOI:10.1016/S0022-328X(00)86812-6

Reference yield:

: 13477-89-9
neodymium(III) chloride hexahydrate

: 97-93-8
triethylaluminum

: NdCl₃*0.5H₂O*0.5((C₂H₅)2Al)2O

: 1069-83-6
tetraethylaluminoxane

Guidance literature:: In toluene; Petroleum ether; byproducts: C2H6; (Ar); using Schlenk techniques; addn. of soln. of (C2H5)3Al (12 equiv.) in petroleum ether to stirred suspn. of NdCl3*6H2O (1 equiv.) in toluenefor 20 min at 40, 50, 70 and 90°C; stirring for 240 min; pptn., filtration, washing of solid twice with toluene and drying under vac., removal of solvent from filtrate in vac., elem. anal.; Kinetics;
DOI:10.1016/S0022-328X(01)01166-4

Reference yield:

: dysprosium(III) chloride hexahydrate

: 97-93-8
triethylaluminum

: DyCl₃*0.5H₂O*0.5((C₂H₅)2Al)2O

: 1069-83-6
tetraethylaluminoxane

Guidance literature:: In toluene; Petroleum ether; byproducts: C2H6; (Ar); using Schlenk techniques; addn. of soln. of (C2H5)3Al (12 equiv.) in petroleum ether to stirred suspn. of DyCl3*6H2O (1 equiv.) in toluenefor 20 min at 40, 50, 70 and 90°C; stirring for 240 min; pptn., filtration, washing of solid twice with toluene and drying under vac., removal of solvent from filtrate in vac., elem. anal.; Kinetics;
DOI:10.1016/S0022-328X(01)01166-4