[5,15-bis[(4'-dimethylaminophenyl)ethynyl]-10,20-diphenylporphinato]Zn(II)

Base Information

Chemical Name:[5,15-bis[(4'-dimethylaminophenyl)ethynyl]-10,20-diphenylporphinato]Zn(II)
CAS No.:184099-41-0
Molecular Formula:C₅₂H₃₈N₆Zn
Molecular Weight:812.304
Hs Code.:

Synonyms:[5,15-bis[(4'-dimethylaminophenyl)ethynyl]-10,20-diphenylporphinato]Zn(II)

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Chemical Property of [5,15-bis[(4'-dimethylaminophenyl)ethynyl]-10,20-diphenylporphinato]Zn(II)

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Technology Process of [5,15-bis[(4'-dimethylaminophenyl)ethynyl]-10,20-diphenylporphinato]Zn(II)

There total 4 articles about [5,15-bis[(4'-dimethylaminophenyl)ethynyl]-10,20-diphenylporphinato]Zn(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 147470-60-8
[5,10-dibromo-10,20-bis-(phenyl)porphyrinato^(2-)]zinc

: 17573-94-3,752235-18-0
4-ethynyl-N,N-dimethylaniline

: 184099-41-0
[5,15-bis[(4'-dimethylaminophenyl)ethynyl]-10,20-diphenylporphinato]Zn(II)

Guidance literature:: With CuI; Pt(PPh₃)4; In tetrahydrofuran; diethylamine; (N2); reaction at room temp. for 12-24 h; chromy., recrystn. (THF/hexanes), drying (24 h, 120°C); elem. anal.;
DOI:10.1021/ja962403y

Reference yield:

: C₅₂H₄₀N₆

: 184099-41-0
[5,15-bis[(4'-dimethylaminophenyl)ethynyl]-10,20-diphenylporphinato]Zn(II)

Guidance literature:: With zinc(II) acetate; In chloroform;
DOI:10.1021/jp205309f

Reference yield:

: 5,15-bis(trimethylsilanylethynyl)-10,20-diphenyl-21H,23H-porphyrin

: 184099-41-0
[5,15-bis[(4'-dimethylaminophenyl)ethynyl]-10,20-diphenylporphinato]Zn(II)

Guidance literature:: Multi-step reaction with 3 steps

1: zinc(II) acetate / dichloromethane

2: tetrabutyl ammonium fluoride / tetrahydrofuran

3: copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine / tetrahydrofuran

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; zinc(II) acetate; tetrabutyl ammonium fluoride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jp205309f