Zn(II)-13-bromo-17,18-dihydro-10-mesityl-18,18-dimethylporphyrin

Base Information

• Chemical Name: Zn(II)-13-bromo-17,18-dihydro-10-mesityl-18,18-dimethylporphyrin
• CAS No.: 892861-66-4
• Molecular Formula: C₃₁H₂₇BrN₄Zn
• Molecular Weight: 600.876
• Mol file: 892861-66-4.mol

Synonyms:Zn(II)-13-bromo-17,18-dihydro-10-mesityl-18,18-dimethylporphyrin

Chemical Property of Zn(II)-13-bromo-17,18-dihydro-10-mesityl-18,18-dimethylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Zn(II)-13-bromo-17,18-dihydro-10-mesityl-18,18-dimethylporphyrin

There total 3 articles about Zn(II)-13-bromo-17,18-dihydro-10-mesityl-18,18-dimethylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

8,9-dibromo-1-formyl-5-mesityldipyrromethane (892861-48-2) + 2-[(3,3,5-trimethyl-3,4-dihydro-2H-pyrrol-2-yl)methyl]pyrrole (276239-53-3) → Zn(II)-13-bromo-17,18-dihydro-10-mesityl-18,18-dimethylporphyrin (892861-66-4)

Guidance literature:

8,9-dibromo-1-formyl-5-mesityldipyrromethane; 2-[(3,3,5-trimethyl-3,4-dihydro-2H-pyrrol-2-yl)methyl]pyrrole; With toluene-4-sulfonic acid; In methanol; dichloromethane; at 20 ℃; for 0.666667h; Inert atmosphere;

With 2,2,6,6-tetramethyl-piperidine; zinc diacetate; silver trifluoromethanesulfonate; In acetonitrile; for 20h; Reflux; Air;

DOI:10.1021/jo9002954

Reference yield:

C31H38Br2N4 → Zn(II)-13-bromo-17,18-dihydro-10-mesityl-18,18-dimethylporphyrin (892861-66-4)

Guidance literature:

With 2,2,6,6-tetramethyl-piperidine; zinc diacetate; silver trifluoromethanesulfonate; In acetonitrile; for 18h; Heating / reflux;

Reference yield:

13-bromo-17,18-dihydro-10-mesityl-18,18-dimethylporphyrin → Zn(II)-13-bromo-17,18-dihydro-10-mesityl-18,18-dimethylporphyrin (892861-66-4)

Guidance literature:

With 2,2,6,6-tetramethyl-piperidine; zinc diacetate; silver trifluoromethanesulfonate; In acetonitrile; for 18h; Reflux;

DOI:10.1021/jo902649d

upstream raw materials:

8,9-dibromo-1-formyl-5-mesityldipyrromethane

2-[(3,3,5-trimethyl-3,4-dihydro-2H-pyrrol-2-yl)methyl]pyrrole

Downstream raw materials:

Zn(II)-13-[2-(triisopropylsilyl)ethynyl]-17,18-dihydro-10-mesityl-18,18-dimethylporphyrin