4-(3-methoxy-benzyloxy)-5-methyl-7-triisopropylsilanyloxymethyl-non-5-en-2-ol

Base Information

Chemical Name:4-(3-methoxy-benzyloxy)-5-methyl-7-triisopropylsilanyloxymethyl-non-5-en-2-ol
CAS No.:854374-68-8
Molecular Formula:C₂₈H₅₀O₄Si
Molecular Weight:478.788
Hs Code.:

Synonyms:4-(3-methoxy-benzyloxy)-5-methyl-7-triisopropylsilanyloxymethyl-non-5-en-2-ol

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Chemical Property of 4-(3-methoxy-benzyloxy)-5-methyl-7-triisopropylsilanyloxymethyl-non-5-en-2-ol

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Technology Process of 4-(3-methoxy-benzyloxy)-5-methyl-7-triisopropylsilanyloxymethyl-non-5-en-2-ol

There total 12 articles about 4-(3-methoxy-benzyloxy)-5-methyl-7-triisopropylsilanyloxymethyl-non-5-en-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 854374-67-7
[2-ethyl-7-(4-methoxy-benzyloxy)-5-(3-methoxy-benzyloxy)-4-methyl-oct-3-enyloxy]triisopropylsilane

: 854374-68-8
4-(3-methoxy-benzyloxy)-5-methyl-7-triisopropylsilanyloxymethyl-non-5-en-2-ol

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; at 0 ℃; for 1h;
DOI:10.1021/ol050588k

Reference yield:

: 854374-57-5
5-(4-methoxy-benzyloxy)-2-methyl-hex-1-en-3-ol

: 854374-68-8
4-(3-methoxy-benzyloxy)-5-methyl-7-triisopropylsilanyloxymethyl-non-5-en-2-ol

Guidance literature:: Multi-step reaction with 6 steps

1: 4-(dimethylamino)pyridine; dicyclohexylcarbodiimide / CH₂Cl₂ / 5 h / 20 °C

2: second-ganeration Grubbs' catalyst / CH₂Cl₂ / 72 h / Heating

3: 92 percent / LiAlH₄ / tetrahydrofuran / 1 h / -78 - 20 °C

4: 100 percent / pyridine / 72 h / 55 °C

5: 100 percent / NaH; imidazole; tetrabutylammonium iodide / tetrahydrofuran; various solvent(s) / 1.5 h / Heating

6: 89 percent / DDQ / CH₂Cl₂; H₂O / 1 h / 0 °C

With pyridine; 1H-imidazole; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; dmap; lithium aluminium tetrahydride; tetra-(n-butyl)ammonium iodide; sodium hydride; dicyclohexyl-carbodiimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/ol050588k

Reference yield:

: 2-ethyl-but-3-enoic acid 1-[2-(4-methoxy-benzyloxy)-propyl]-2-methyl-allyl ester

: 854374-68-8
4-(3-methoxy-benzyloxy)-5-methyl-7-triisopropylsilanyloxymethyl-non-5-en-2-ol

Guidance literature:: Multi-step reaction with 5 steps

1: 75 percent / second-ganeration Grubbs' catalyst / CH₂Cl₂ / 72 h / Heating

2: 92 percent / LiAlH₄ / tetrahydrofuran / 1 h / -78 - 20 °C

3: 100 percent / pyridine / 72 h / 55 °C

4: 100 percent / NaH; imidazole; tetrabutylammonium iodide / tetrahydrofuran; various solvent(s) / 1.5 h / Heating

5: 89 percent / DDQ / CH₂Cl₂; H₂O / 1 h / 0 °C

With pyridine; 1H-imidazole; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; lithium aluminium tetrahydride; tetra-(n-butyl)ammonium iodide; sodium hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/ol050588k