2--7-tosyl-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole

Base Information

Chemical Name:2--7-tosyl-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole
CAS No.:101678-89-1
Molecular Formula:C₂₅H₂₈N₂O₃S₃
Molecular Weight:500.707
Hs Code.:

2-<bis(methylthio)acetyl>-7-tosyl-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole

Synonyms:2--7-tosyl-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole

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Chemical Property of 2--7-tosyl-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole

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Technology Process of 2--7-tosyl-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole

There total 5 articles about 2--7-tosyl-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 128902-27-2,128948-97-0
2--7-tosyl-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole

: 101678-89-1
2--7-tosyl-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; for 40h; Heating;
DOI:10.1021/jo00313a017

Reference yield:

: 99552-97-3
1,2,3,4,5,6-hexahydro-1,5-methaneoazacino<4,3-b>indole

: 101678-89-1
2--7-tosyl-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole

Guidance literature:: Multi-step reaction with 4 steps

1: 1N NaOH / CH₂Cl₂

2: 50percent NaOH / Bu₄N*HSO₄ / benzene

3: m-CPBA, NaHCO₃ / CH₂Cl₂

4: TFAA, Et₃N / from 0 deg C to 135 deg C

With sodium hydroxide; sodium hydrogencarbonate; triethylamine; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic anhydride; tetra(n-butyl)ammonium hydrogensulfate; In dichloromethane; benzene;
DOI:10.1016/S0040-4039(00)94994-3

Reference yield:

: 128902-24-9
2-<(methylthio)acetyl>-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole

: 101678-89-1
2--7-tosyl-1,2,3,4,5,6-hexahydro-1,5-methanoazocino<4,3-b>indole

Guidance literature:: Multi-step reaction with 3 steps

1: 50percent NaOH / Bu₄N*HSO₄ / benzene

2: m-CPBA, NaHCO₃ / CH₂Cl₂

3: TFAA, Et₃N / from 0 deg C to 135 deg C

With sodium hydroxide; sodium hydrogencarbonate; triethylamine; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic anhydride; tetra(n-butyl)ammonium hydrogensulfate; In dichloromethane; benzene;
DOI:10.1016/S0040-4039(00)94994-3