(R)-N-allyl-N-phenyl tert-butanesulfinamide

Base Information

Chemical Name:(R)-N-allyl-N-phenyl tert-butanesulfinamide
CAS No.:1372133-79-3
Molecular Formula:C₁₃H₁₉NOS
Molecular Weight:237.366
Hs Code.:

Synonyms:(R)-N-allyl-N-phenyl tert-butanesulfinamide

Suppliers and Price of (R)-N-allyl-N-phenyl tert-butanesulfinamide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-N-allyl-N-phenyl tert-butanesulfinamide

Chemical Property:

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Technology Process of (R)-N-allyl-N-phenyl tert-butanesulfinamide

There total 4 articles about (R)-N-allyl-N-phenyl tert-butanesulfinamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 106-95-6
allyl bromide

: (R)-2-methyl-N-phenylpropane-2-sulfinamide

: 1372133-79-3
(R)-N-allyl-N-phenyl tert-butanesulfinamide

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 25 ℃; for 0.25h; Schlenk technique;
DOI:10.1021/acs.orglett.1c03221

Reference yield:

: 108-86-1,52753-63-6
bromobenzene

: 1372133-79-3
(R)-N-allyl-N-phenyl tert-butanesulfinamide

Guidance literature:: Multi-step reaction with 2 steps

1.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; di-tert-butyl (2',4',6'-triisopropylbiphenyl-2-yl)phosphine; water; sodium hydroxide / toluene / 20 h / 90 °C / Inert atmosphere

2.1: sodium hydride / tetrahydrofuran; mineral oil / 1 h / Cooling with ice; Inert atmosphere

2.2: Inert atmosphere

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; di-tert-butyl (2',4',6'-triisopropylbiphenyl-2-yl)phosphine; water; sodium hydride; sodium hydroxide; In tetrahydrofuran; toluene; mineral oil;
DOI:10.1021/jo3003584

Reference yield:

: 133497-27-5
(±)-2-methyl-N-phenylpropane-2-sulfinamide

: 1372133-79-3
(R)-N-allyl-N-phenyl tert-butanesulfinamide

Guidance literature:: Multi-step reaction with 2 steps

1: dihydroquinine / chloroform; 1,2-dichloro-ethane / 180 h / -40 °C / Schlenk technique; Molecular sieve; Resolution of racemate

2: sodium hydride / N,N-dimethyl-formamide / 0.25 h / 25 °C / Schlenk technique

With sodium hydride; dihydroquinine; In chloroform; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
DOI:10.1021/acs.orglett.1c03221