cyclohepta-2,4,6-trienylmethyl-dimethyl-phenyl-silane

Base Information

• Chemical Name: cyclohepta-2,4,6-trienylmethyl-dimethyl-phenyl-silane
• CAS No.: 1067080-21-0
• Molecular Formula: C₁₆H₂₀Si
• Molecular Weight: 240.42
• Mol file: 1067080-21-0.mol

Synonyms:cyclohepta-2,4,6-trienylmethyl-dimethyl-phenyl-silane

Chemical Property of cyclohepta-2,4,6-trienylmethyl-dimethyl-phenyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cyclohepta-2,4,6-trienylmethyl-dimethyl-phenyl-silane

There total 2 articles about cyclohepta-2,4,6-trienylmethyl-dimethyl-phenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

chloromethyldimethylphenylsilane (1833-51-8) + cycloheptatrienylium tetrafluoroborate (27081-10-3) → cyclohepta-2,4,6-trienylmethyl-dimethyl-phenyl-silane (1067080-21-0)

Guidance literature:

chloromethyldimethylphenylsilane; With iodine; magnesium; In diethyl ether; Inert atmosphere; Reflux;

cycloheptatrienylium tetrafluoroborate; In diethyl ether; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/ol8016403

Reference yield: 64.0%

chloromethyldimethylphenylsilane (1833-51-8) + tropylium tetrafluoroborate (27081-10-3) → cyclohepta-2,4,6-trienylmethyl-dimethyl-phenyl-silane (1067080-21-0)

Guidance literature:

chloromethyldimethylphenylsilane; With iodine; magnesium; In diethyl ether; Reflux;

tropylium tetrafluoroborate; In diethyl ether; at -78 - 20 ℃;

DOI:10.1021/jo101945h

Reference yield: 27.0%

cyclohepta-2,4,6-trienylmethyl-dimethyl-phenyl-silane (1067080-21-0) → 7-((dimethyl(phenyl)silyl)methyl)cyclohepta-3,5-diene-1,2-diol + 6-((dimethyl(phenyl)silyl)methyl)-7-hydroxycyclohepta-2,4-dienone

Guidance literature:

With Quinuclidine; potassium osmate(VI) dihydrate; methanesulfonamide; potassium carbonate; potassium hexacyanoferrate(III); In water; acetonitrile; at 20 ℃; for 12h; diastereoselective reaction;

DOI:10.1021/jo101945h

upstream raw materials:

chloromethyldimethylphenylsilane

cycloheptatrienylium tetrafluoroborate

tropylium tetrafluoroborate