p-<<(Nitrophenyl)sulfonyl>oxy>acetone

Base Information

• Chemical Name: p-<<(Nitrophenyl)sulfonyl>oxy>acetone
• CAS No.: 98990-66-0
• Molecular Formula: C₉H₉NO₆S
• Molecular Weight: 259.24
• Mol file: 98990-66-0.mol

Synonyms:p-<<(Nitrophenyl)sulfonyl>oxy>acetone

Chemical Property of p-<<(Nitrophenyl)sulfonyl>oxy>acetone

Chemical Property:

Purity/Quality:

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Technology Process of p-<<(Nitrophenyl)sulfonyl>oxy>acetone

There total 4 articles about p-<<(Nitrophenyl)sulfonyl>oxy>acetone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

Isopropenyl acetate (108-22-5) + 4-nitrobenzenesulfonyl peroxide (6209-72-9) → p-<<(Nitrophenyl)sulfonyl>oxy>acetone (98990-66-0)

Guidance literature:

With methanol; In ethyl acetate; at 0 ℃; for 24h;

DOI:10.1055/s-1985-31337

Reference yield: 73.0%

tert-Butyl 2-<<(p-nitrophenyl)sulfonyl>oxy>acetoacetate (124716-82-1) → p-<<(Nitrophenyl)sulfonyl>oxy>acetone (98990-66-0)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; for 3h; Ambient temperature;

DOI:10.1021/jo00291a030

Reference yield: 30.0%

2-(Trimethylsilyloxy)propene (1833-53-0) + 4-nitrobenzenesulfonyl peroxide (6209-72-9) → p-<<(Nitrophenyl)sulfonyl>oxy>acetone (98990-66-0)

Guidance literature:

With water; In ethyl acetate; for 29h; Ambient temperature;

DOI:10.1021/jo00225a034

upstream raw materials:

Isopropenyl acetate

4-nitrobenzenesulfonyl peroxide

2-(Trimethylsilyloxy)propene

tert-Butyl 2-<<(p-nitrophenyl)sulfonyl>oxy>acetoacetate