Technology Process of C57H100O7Si4
There total 17 articles about C57H100O7Si4 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
dichloromethane; water;
at 20 ℃;
for 1h;
DOI:10.1080/00397911.2010.516462
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 2,6-dimethylpyridine
2: hydrogenchloride / isopropyl alcohol / 6 h / 70 °C
3: oxalyl dichloride; dimethyl sulfoxide
4: lithium hexamethyldisilazane / 1 h / -78 °C
5: 2,6-dimethylpyridine
6: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 1 h / 20 °C
With
2,6-dimethylpyridine; hydrogenchloride; oxalyl dichloride; dimethyl sulfoxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium hexamethyldisilazane;
In
dichloromethane; water; isopropyl alcohol;
3: Swern oxidation;
DOI:10.1080/00397911.2010.516462
- Guidance literature:
-
Multi-step reaction with 10 steps
1: potassium hydride / tetrahydrofuran
2: sodium periodate; osmium(VIII) oxide; 4-methylmorpholine N-oxide
3: lithium diisopropyl amide
4: acetic acid; tetramethylammonium triacetoxyborohydride / acetonitrile / 22 h / -30 °C
5: 2,6-dimethylpyridine
6: hydrogenchloride / isopropyl alcohol / 6 h / 70 °C
7: oxalyl dichloride; dimethyl sulfoxide
8: lithium hexamethyldisilazane / 1 h / -78 °C
9: 2,6-dimethylpyridine
10: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 1 h / 20 °C
With
2,6-dimethylpyridine; hydrogenchloride; sodium periodate; osmium(VIII) oxide; oxalyl dichloride; potassium hydride; acetic acid; dimethyl sulfoxide; 4-methylmorpholine N-oxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium hexamethyldisilazane; tetramethylammonium triacetoxyborohydride; lithium diisopropyl amide;
In
tetrahydrofuran; dichloromethane; water; isopropyl alcohol; acetonitrile;
3: Aldol addition / 7: Swern oxidation;
DOI:10.1080/00397911.2010.516462
