benzyl O--(2->3)-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Base Information

• Chemical Name: benzyl O--(2->3)-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside
• CAS No.: 96520-22-8
• Molecular Formula: C₇₄H₈₅NO₂₃
• Molecular Weight: 1356.48
• Mol file: 96520-22-8.mol

Synonyms:benzyl O--(2->3)-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Chemical Property of benzyl O--(2->3)-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl O--(2->3)-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

There total 14 articles about benzyl O--(2->3)-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

C74H83NO23 (145240-81-9) → benzyl O--(2->3)-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (96520-22-8)

Guidance literature:

With hydrogenchloride; sodium cyanoborohydride;

DOI:10.1016/S0040-4039(00)60022-9

Reference yield: 55.0%

benzyl 2,3,6-tri-O-benzyl-4-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranoside (94926-36-0) + 5-acetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-1-(methoxycarbonyl)-D-glycero-α-D-galacto-2-nonulopyranosyl diethyl phosphite (145240-79-5) → benzyl O--(2->3)-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (96520-22-8)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In acetonitrile; at -40 ℃;

DOI:10.1016/S0040-4039(00)60022-9

Reference yield: 55.0%

benzyl 2,3,6-tri-O-benzyl-4-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranoside (94926-36-0) + (2R,4S,5R,6R)-4-Acetoxy-5-acetylamino-2-(diethoxy-phosphoryloxy)-6-((1S,2R)-1,2,3-triacetoxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester → benzyl O--(2->3)-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (96520-22-8)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In acetonitrile; at -40 ℃; for 1h;

upstream raw materials:

Pyranosylbromid

benzyl 2,3,6-tri-O-benzyl-4-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranoside

N-acetyl-4,7,8,9-tetra-O-acetyl-2-chloro-2-deoxyneuraminic acid methyl ester

5-acetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-1-(methoxycarbonyl)-D-glycero-α-D-galacto-2-nonulopyranosyl diethyl phosphite

Downstream raw materials:

Benzyl-O-glycero-β-<*>-galacto-2-nonulopyranosyl)onat>-(2->3)-O-(2,6-di-O-benzyl-β-<*>-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-<*>-glucopyranosid

Benzyl-O-(5-acetamido-3,5-didesoxy-<*>-glycero-β-<*>-galacto-2-nonulopyranosylons<*>ure)-(2->3)-O-(2,6-di-O-benzyl-β-<*>-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-<*>-glucopyranosid

Benzyl-O--glycero-α-<*>-galacto-2-nonulopyranosyl)onat>-(2->3)-O-(2,6-di-O-benzyl-β-<*>-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-<*>-glucopyranosid

Benzyl-O-(5-acetamido-3,5-didesoxy-<*>-glycero-α-<*>-galacto-2-nonulopyranosylons<*>ure)-(2->3)-O-(2,6-di-O-benzyl-β-<*>-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-<*>-glucopyranosid