3-C-allyl-5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxyphenylmethyl)-α-D-ribo-hex-5-enofuranose

Base Information

Chemical Name:3-C-allyl-5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxyphenylmethyl)-α-D-ribo-hex-5-enofuranose
CAS No.:380488-77-7
Molecular Formula:C₂₀H₂₆O₅
Molecular Weight:346.423
Hs Code.:

Synonyms:3-C-allyl-5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxyphenylmethyl)-α-D-ribo-hex-5-enofuranose

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Chemical Property of 3-C-allyl-5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxyphenylmethyl)-α-D-ribo-hex-5-enofuranose

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Technology Process of 3-C-allyl-5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxyphenylmethyl)-α-D-ribo-hex-5-enofuranose

There total 5 articles about 3-C-allyl-5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxyphenylmethyl)-α-D-ribo-hex-5-enofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 380488-86-8
Methanesulfonic acid (R)-1-[(3aR,5R,6R,6aR)-6-allyl-6-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-2-methanesulfonyloxy-ethyl ester

: 380488-77-7
3-C-allyl-5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxyphenylmethyl)-α-D-ribo-hex-5-enofuranose

Guidance literature:: With sodium iodide; In butanone; for 8h; Heating;
DOI:10.1021/jo010718c

Reference yield:

: 2746-25-0
p-Methoxybenzyl bromide

: 380488-77-7
3-C-allyl-5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxyphenylmethyl)-α-D-ribo-hex-5-enofuranose

Guidance literature:: Multi-step reaction with 4 steps

1: 86 percent / NaH / tetrahydrofuran / 6 h / 20 °C

2: 75 percent / 0.8percent H₂SO₄ / methanol / 10 h / 20 °C

3: Et₃N; DMAP / CH₂Cl₂ / 1 h / 20 °C

4: 64 percent / NaI / butan-2-one / 8 h / Heating

With dmap; sodium hydride; triethylamine; sodium iodide; In tetrahydrofuran; methanol; dichloromethane; butanone;
DOI:10.1021/jo010718c

Reference yield:

: 175877-45-9
3-C-allyl-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

: 380488-77-7
3-C-allyl-5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxyphenylmethyl)-α-D-ribo-hex-5-enofuranose

Guidance literature:: Multi-step reaction with 4 steps

1: 86 percent / NaH / tetrahydrofuran / 6 h / 20 °C

2: 75 percent / 0.8percent H₂SO₄ / methanol / 10 h / 20 °C

3: Et₃N; DMAP / CH₂Cl₂ / 1 h / 20 °C

4: 64 percent / NaI / butan-2-one / 8 h / Heating

With dmap; sodium hydride; triethylamine; sodium iodide; In tetrahydrofuran; methanol; dichloromethane; butanone;
DOI:10.1021/jo010718c