8-(2'-aminobiphenyl-4-ylmethoxy)-3,5,10-trioxatricyclo[6.2.1.0^2,6]undecane-4,9-dione

Base Information

• Chemical Name: 8-(2'-aminobiphenyl-4-ylmethoxy)-3,5,10-trioxatricyclo[6.2.1.0^2,6]undecane-4,9-dione
• CAS No.: 859224-79-6
• Molecular Formula: C₂₁H₁₉NO₆
• Molecular Weight: 381.385

Synonyms:8-(2'-aminobiphenyl-4-ylmethoxy)-3,5,10-trioxatricyclo[6.2.1.0^2,6]undecane-4,9-dione

Chemical Property of 8-(2'-aminobiphenyl-4-ylmethoxy)-3,5,10-trioxatricyclo[6.2.1.0^2,6]undecane-4,9-dione

Chemical Property:

Purity/Quality:

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Technology Process of 8-(2'-aminobiphenyl-4-ylmethoxy)-3,5,10-trioxatricyclo[6.2.1.0^2,6]undecane-4,9-dione

There total 4 articles about 8-(2'-aminobiphenyl-4-ylmethoxy)-3,5,10-trioxatricyclo[6.2.1.0^2,6]undecane-4,9-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1R,2S,6R,8R)-8-(2'-Nitro-biphenyl-4-ylmethoxy)-3,5,10-trioxa-tricyclo[6.2.1.02,6]undecane-4,9-dione (859224-86-5) → 8-(2'-aminobiphenyl-4-ylmethoxy)-3,5,10-trioxatricyclo[6.2.1.02,6]undecane-4,9-dione (859224-79-6)

Guidance literature:

With tin(ll) chloride; In ethanol; N,N-dimethyl-formamide; at 20 ℃;

DOI:10.1021/jm050049l

Reference yield:

(3aS,4R,7R,8aR)-7-hydroxytetrahydro-4,7-methano[1,3]dioxolo[4,5-c]oxepine-2,6(4H)-dione (859224-74-1) → 8-(2'-aminobiphenyl-4-ylmethoxy)-3,5,10-trioxatricyclo[6.2.1.02,6]undecane-4,9-dione (859224-79-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: NaH / dimethylformamide / 0.5 h / 0 °C

1.2: dimethylformamide / 0 - 20 °C

2.1: 3.1 g / SnCl₂*2H₂O / ethanol; dimethylformamide / 20 °C

With sodium hydride; tin(ll) chloride; In ethanol; N,N-dimethyl-formamide;

DOI:10.1021/jm050049l

Reference yield:

D-(-)-quinic acid (77-95-2) → 8-(2'-aminobiphenyl-4-ylmethoxy)-3,5,10-trioxatricyclo[6.2.1.02,6]undecane-4,9-dione (859224-79-6)

Guidance literature:

Multi-step reaction with 4 steps

1.1: 93 percent / p-toluenesulfonic acid / dimethylformamide; benzene / 25 h / Heating

2.1: 76 percent / pyridine / 2 h / 20 °C

3.1: NaH / dimethylformamide / 0.5 h / 0 °C

3.2: dimethylformamide / 0 - 20 °C

4.1: 3.1 g / SnCl₂*2H₂O / ethanol; dimethylformamide / 20 °C

With pyridine; sodium hydride; toluene-4-sulfonic acid; tin(ll) chloride; In ethanol; N,N-dimethyl-formamide; benzene;

DOI:10.1021/jm050049l

upstream raw materials:

(1R,2S,6R,8R)-8-(2'-Nitro-biphenyl-4-ylmethoxy)-3,5,10-trioxa-tricyclo[6.2.1.0^2,6]undecane-4,9-dione

(3aS,4R,7R,8aR)-7-hydroxytetrahydro-4,7-methano[1,3]dioxolo[4,5-c]oxepine-2,6(4H)-dione

D-(-)-quinic acid

1,5-quinide

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