Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester

Base Information

Chemical Name:Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester
CAS No.:208586-60-1
Molecular Formula:C₁₇H₂₄O₅
Molecular Weight:308.375
Hs Code.:

Synonyms:Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester

Suppliers and Price of Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 2 raw suppliers

Chemical Property of Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

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Hazard Codes:

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Technology Process of Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester

There total 8 articles about Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 108-05-4,9003-20-7
vinyl acetate

: 208586-48-5
(E)-(S)-6-(4-Methoxy-benzyloxy)-2-methyl-hex-2-ene-1,4-diol

: 208586-60-1
Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester

Guidance literature:: In tetrahydrofuran; at 0 ℃; for 24h; PFL enzyme;
DOI:10.1016/S0040-4039(98)00500-0

Reference yield:

: 208586-56-5
(S)-5-(4-Methoxy-benzyloxy)-pent-1-yn-3-ol

: 208586-60-1
Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: HMDS / tetrahydrofuran / 2 h / Ambient temperature

2: 1.55N BuLi / tetrahydrofuran; hexane / 7 h / -78 deg C to rt

3: HF*pyridine / tetrahydrofuran

4: 1.) CuI, 2.) NEt₃, DMAP, 3.) Na₂S*9H₂O / 1.) THF, 0-4 deg C, 2 d, 2.) CH₂Cl₂, -78 deg C to rt, 7 h, 3.) EtOH, rt, 4 d

5: 100 percent / tetrahydrofuran / 24 h / 0 °C / PFL enzyme

With dmap; sodium sulfide; copper(l) iodide; n-butyllithium; pyridine hydrogenfluoride; triethylamine; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; hexane;
DOI:10.1016/S0040-4039(98)00500-0

Reference yield:

: 208586-55-4
(S)-pent-4-yn-1,3-diol

: 208586-60-1
Acetic acid (E)-(S)-4-hydroxy-6-(4-methoxy-benzyloxy)-2-methyl-hex-2-enyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 47 percent / PPTS / tetrahydrofuran / 48 h / Ambient temperature

2: HMDS / tetrahydrofuran / 2 h / Ambient temperature

3: 1.55N BuLi / tetrahydrofuran; hexane / 7 h / -78 deg C to rt

4: HF*pyridine / tetrahydrofuran

5: 1.) CuI, 2.) NEt₃, DMAP, 3.) Na₂S*9H₂O / 1.) THF, 0-4 deg C, 2 d, 2.) CH₂Cl₂, -78 deg C to rt, 7 h, 3.) EtOH, rt, 4 d

6: 100 percent / tetrahydrofuran / 24 h / 0 °C / PFL enzyme

With dmap; sodium sulfide; copper(l) iodide; n-butyllithium; pyridinium p-toluenesulfonate; pyridine hydrogenfluoride; triethylamine; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; hexane;
DOI:10.1016/S0040-4039(98)00500-0