Triisopropyl-[(1R,2S,6S)-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]hept-2-yloxy]-silane

Base Information

Chemical Name:Triisopropyl-[(1R,2S,6S)-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]hept-2-yloxy]-silane
CAS No.:152231-18-0
Molecular Formula:C₂₂H₃₆O₄SSi
Molecular Weight:424.677
Hs Code.:

Synonyms:Triisopropyl-[(1R,2S,6S)-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]hept-2-yloxy]-silane

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Chemical Property of Triisopropyl-[(1R,2S,6S)-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]hept-2-yloxy]-silane

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Technology Process of Triisopropyl-[(1R,2S,6S)-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]hept-2-yloxy]-silane

There total 5 articles about Triisopropyl-[(1R,2S,6S)-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]hept-2-yloxy]-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 152231-18-0
Triisopropyl-[(1R,2S,6S)-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]hept-2-yloxy]-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / 2,6-lutidine

2: LiOOt-Bu / tetrahydrofuran / 4 h / Ambient temperature

With 2,6-dimethylpyridine; lithium tert-butyl hydroperoxide; In tetrahydrofuran;
DOI:10.1016/S0040-4039(00)74070-6

Reference yield:

: 140710-34-5
(S)-2-p-Tolylsulfanyl-cyclohex-2-enol

: 152231-18-0
Triisopropyl-[(1R,2S,6S)-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]hept-2-yloxy]-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / MCPBA / CH₂Cl₂ / Ambient temperature

2: 97 percent / 2,6-lutidine

3: LiOOt-Bu / tetrahydrofuran / 4 h / Ambient temperature

With 2,6-dimethylpyridine; lithium tert-butyl hydroperoxide; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(00)74070-6

Reference yield:

: 140710-30-1
(S)-2-p-tolylsulfenyl-2-cyclohexenyl acetate

: 152231-18-0
Triisopropyl-[(1R,2S,6S)-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]hept-2-yloxy]-silane

Guidance literature:: Multi-step reaction with 4 steps

1: NaOH / methanol / Ambient temperature

2: 91 percent / MCPBA / CH₂Cl₂ / Ambient temperature

3: 97 percent / 2,6-lutidine

4: LiOOt-Bu / tetrahydrofuran / 4 h / Ambient temperature

With 2,6-dimethylpyridine; sodium hydroxide; lithium tert-butyl hydroperoxide; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/S0040-4039(00)74070-6