(1S)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl 2,4-dimethoxy-6-vinylbenzoate

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Chemical Name:(1S)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl 2,4-dimethoxy-6-vinylbenzoate
CAS No.:1333419-91-2
Molecular Formula:C₂₇H₄₀O₆
Molecular Weight:460.611
Hs Code.:

Synonyms:(1S)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl 2,4-dimethoxy-6-vinylbenzoate

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Chemical Property of (1S)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl 2,4-dimethoxy-6-vinylbenzoate

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Technology Process of (1S)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl 2,4-dimethoxy-6-vinylbenzoate

There total 15 articles about (1S)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl 2,4-dimethoxy-6-vinylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1204755-29-2
4,6-dimethoxy-2-vinyl-benzoic acid

: 1333419-85-4
(2R)-6-(tetrahydro-2H-2-pyranyloxy)-10-undecen-2-ol

: 1333419-91-2
(1S)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl 2,4-dimethoxy-6-vinylbenzoate

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In diethyl ether; benzene; at 20 ℃; for 14h;
DOI:10.1055/s-0030-1260058

Reference yield:

: 855256-87-0
(5R)-5-[1-(tert-butyl)-1,1-diphenylsilyl]oxyhexanal

: 1333419-91-2
(1S)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl 2,4-dimethoxy-6-vinylbenzoate

Guidance literature:: Multi-step reaction with 4 steps

1.1: magnesium / tetrahydrofuran / 0.5 h / 20 - 25 °C / Inert atmosphere

1.2: 1 h / Inert atmosphere

2.1: pyridinium p-toluenesulfonate / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 5 h / 0 - 20 °C / Inert atmosphere

4.1: triphenylphosphine; diethylazodicarboxylate / diethyl ether; benzene / 14 h / 20 °C

With tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; magnesium; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; diethyl ether; dichloromethane; benzene; 1.2: Grignard reaction / 4.1: Mitsunobu reaction;
DOI:10.1055/s-0030-1260058

Reference yield:

: 929626-53-9
(2S)-2-[4-(2-oxiranyl)butoxy]tetrahydro-2H-pyran

: 1333419-91-2
(1S)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl 2,4-dimethoxy-6-vinylbenzoate

Guidance literature:: Multi-step reaction with 8 steps

1.1: lithium aluminium tetrahydride / tetrahydrofuran / 4 h / 0 - 20 °C / Inert atmosphere

2.1: 1H-imidazole; dmap / dichloromethane / 4 h / 0 - 25 °C / Inert atmosphere

3.1: pyridinium p-toluenesulfonate / ethanol / 1 h / 60 °C

4.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dichloromethane; dimethyl sulfoxide / 0.5 h / 20 °C / Inert atmosphere

5.1: magnesium / tetrahydrofuran / 0.5 h / 20 - 25 °C / Inert atmosphere

5.2: 1 h / Inert atmosphere

6.1: pyridinium p-toluenesulfonate / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

7.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 5 h / 0 - 20 °C / Inert atmosphere

8.1: triphenylphosphine; diethylazodicarboxylate / diethyl ether; benzene / 14 h / 20 °C

With 1H-imidazole; dmap; lithium aluminium tetrahydride; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; magnesium; triphenylphosphine; diethylazodicarboxylate; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; dimethyl sulfoxide; benzene; 5.2: Grignard reaction / 8.1: Mitsunobu reaction;
DOI:10.1055/s-0030-1260058