acetylide substituted sila[1]ferrocenophane

Base Information

Chemical Name:acetylide substituted sila[1]ferrocenophane
CAS No.:475139-19-6
Molecular Formula:C₁₉H₁₆FeSi
Molecular Weight:328.269
Hs Code.:

Synonyms:acetylide substituted sila[1]ferrocenophane

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Chemical Property of acetylide substituted sila[1]ferrocenophane

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Technology Process of acetylide substituted sila[1]ferrocenophane

There total 1 articles about acetylide substituted sila[1]ferrocenophane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 174872-97-0
1,1-chloro(methyl)-1-sila-[1]ferrocenophane

: 4440-01-1
lithium phenylacetylide

: 475139-19-6
acetylide substituted sila[1]ferrocenophane

Guidance literature:: In diethyl ether; byproducts: LiCl; N2; dropwise addn. of lithium acetilyde suspn. in diethyl ether to soln.of ferrocenophane in diethyl ether at -78°C, warming to room tem p., stirring for 1 h; filtering, removal of volatiles under vac., recrystn. from hexanes/toluene (50:50) at -30°C; elem. anal.;
DOI:10.1021/om0204078

Reference yield: 93.0%

: 475139-19-6
acetylide substituted sila[1]ferrocenophane

: [Fe(η5-C5H4)2Si(Me)(CCPh)](n)

Guidance literature:: With platinum-divinyltetramethyldisiloxane complex; In toluene; N2; addn. of a soln. of catalyst (platinum-divinyltetramethyldisiloxane)(0.3 mol. %) in xylenes to a stirred toluene soln. of ferrocenophane, s tirring for 20 h; pptn. into stirred methanol, washing the ppt. three times with hexanes, drying under vac.; elem. anal.;
DOI:10.1021/om0204078

Reference yield: 65.0%

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 475139-19-6
acetylide substituted sila[1]ferrocenophane

: [Fe(η-C5H4)2Si(Me)(Co2(CO)6C2Ph)]

Guidance literature:: In hexane; byproducts: CO; under N2; Co2(CO)8 in hexanes added dropwise to stirred soln. of Fe(η-C5H4)2Si(Me)C2Ph in hexanes; react. mixt. stirred at 25 °C for 2 h; product pptd. by cooling react. mixt. to -55 °C; elem. anal.;
DOI:10.1021/om030352p